Hua-Fen Hsu &ndash; Research Output

2018

Activation of O−H and C−O Bonds in Water and Methanol by a Vanadium-Bound Thiyl Radical

Yan, J. A., Yang, Z. K., Chen, Y. S., Chang, Y. H., Lyu, C. L., Luo, C. G., Cheng, M-J. & Hsu, H-F., 2018 Oct 12, In : Chemistry - A European Journal. 24, 57, p. 15190-15194 5 p.

Research output: Contribution to journal › Article

Vanadium

Carbon Monoxide

Methanol

Chemical activation

Water

2017

1 Citation (Scopus)

Redox Interconversion of Non-Oxido Vanadium Complexes Accompanied by Acid-Base Chemistry of Thiol and Thiolate

Yan, J. A., Chen, Y. S., Chang, Y. H., Tsai, C. Y., Lyu, C. L., Luo, C. G., Lee, G. H. & Hsu, H-F., 2017 Aug 7, In : Inorganic Chemistry. 56, 15, p. 9055-9063 9 p.

Research output: Contribution to journal › Article

Vanadium

Sulfhydryl Compounds

thiols

vanadium

chemistry

1 Citation (Scopus)

Spin-Polarization-Induced Preedge Transitions in the Sulfur K-Edge XAS Spectra of Open-Shell Transition-Metal Sulfates: Spectroscopic Validation of σ-Bond Electron Transfer

Frank, P., Szilagyi, R. K., Gramlich, V., Hsu, H-F., Hedman, B. & Hodgson, K. O., 2017 Feb 6, In : Inorganic Chemistry. 56, 3, p. 1080-1093 14 p.

Research output: Contribution to journal › Article

Spin polarization

X ray absorption spectroscopy

Sulfur

Sulfates

Transition metals

2016

A non-oxo methanolate-bridged divanadium(IV) complex with tris(2-sulfanidylphenyl)phosphane ligands: Synthesis, structural characterization and magnetic investigation

Wu, H. M., Chang, Y. H., Su, C. L., Lee, G. H. & Hsu, H-F., 2016 May 1, In : Acta Crystallographica Section C: Structural Chemistry. 72, 5, p. 416-420 5 p.

Research output: Contribution to journal › Article

phosphine

Vanadium

vanadium

Ligands

ligands

3 Citations (Scopus)

Reactivity of a Fe(III)-Bound Methoxide Supported with a Tris(thiolato)phosphine Ligand: Activation of C-Cl Bond in CH₂Cl₂ by Nucleophilic Attack of a Fe(III)-OCH₃ Moiety

Chang, K. C., Huang, C. J., Chang, Y. H., Wu, Z. H., Kuo, T. S. & Hsu, H-F., 2016 Jan 19, In : Inorganic Chemistry. 55, 2, p. 566-572 7 p.

Research output: Contribution to journal › Article

phosphine

Nucleophiles

X ray crystallography

Crystal symmetry

phosphines

2015

2 Citations (Scopus)

Non-oxido divanadium(iv) and divanadium(v) thiolate complexes with a new type of chalcogenide bridging motif

Wu, H. M., Chang, Y. H., Tsai, Y. F., Hsu, K-F., Lee, G. H. & Hsu, H-F., 2015 Mar 14, In : Dalton Transactions. 44, 10, p. 4468-4473 6 p.

Research output: Contribution to journal › Article

Vanadium

Chalcogens

Ions

Metals

Chemical activation

2014

12 Citations (Scopus)

Catalytic reduction of hydrazine to ammonia by a mononuclear iron(II) complex on a tris(thiolato)phosphine platform

Chang, Y. H., Chan, P. M., Tsai, Y. F., Lee, G. H. & Hsu, H-F., 2014 Jan 21, In : Inorganic Chemistry. 53, 2, p. 664-666 3 p.

Research output: Contribution to journal › Article

phosphine

hydrazine

Nitrogenase

hydrazines

Ammonia

43 Citations (Scopus)

Oligonucleotides-assembled au nanorod-assisted cancer photothermal ablation and combination chemotherapy with targeted dual-drug delivery of doxorubicin and cisplatin prodrug

Shanmugam, V., Chien, Y. H., Cheng, Y. S., Liu, T. Y., Huang, C-C., Su, C. H., Chen, Y. S., Kumar, U., Hsu, H-F. & Yeh, C-S., 2014 Mar 26, In : ACS Applied Materials and Interfaces. 6, 6, p. 4382-4393 12 p.

Research output: Contribution to journal › Article

Chemotherapy

Oligonucleotides

Prodrugs

Ablation

Nanorods

2013

6 Citations (Scopus)

Activation of dichloromethane by a V(iii) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate

Chen, T. T., Chen, Y. S., Chang, Y. H., Wang, J. C., Tsai, Y. F., Lee, G. H., Kuo, T. S. & Hsu, H-F., 2013 Feb 4, In : Chemical Communications. 49, 11, p. 1109-1111 3 p.

Research output: Contribution to journal › Article

Methylene Chloride

Dichloromethane

Reaction products

Sulfur

Transition metals

16 Citations (Scopus)

Synthesis, structural characterization, encapsulation in zeolite y and catalytic activity of an oxidovanadium(V) complex with a tribasic pentadentate ligand

Maurya, M. R., Bisht, M., Chaudhary, N., Avecilla, F., Kumar, U. & Hsu, H-F., 2013 Apr 30, In : Polyhedron. 54, p. 180-188 9 p.

Research output: Contribution to journal › Article

Zeolites

Encapsulation

styrenes

catalytic activity

sulfides

2012

11 Citations (Scopus)

The binding nature of humic substances with arsenic in alluvial aquifers of Chianan Plain, southwestern Taiwan

Selim Reza, A. H. M., Jean, J-S., Lee, M. K., Kulp, T. R., Hsu, H-F., Liu, C. C. & Lee, Y. C., 2012 Mar 1, In : Journal of Geochemical Exploration. 114, p. 98-108 11 p.

Research output: Contribution to journal › Article

Humic Substances

Arsenic

humic substance

Aquifers

arsenic

2011

28 Citations (Scopus)

A comparative study on arsenic and humic substances in alluvial aquifers of Bengal delta plain (NW Bangladesh), Chianan plain (SW Taiwan) and Lanyang plain (NE Taiwan): Implication of arsenic mobilization mechanisms

Reza, A. H. M. S., Jean, J-S., Yang, H-J., Lee, M. K., Hsu, H-F., Liu, C. C., Lee, Y. C., Bundschuh, J., Lin, K. H. & Lee, C. Y., 2011 Jun 1, In : Environmental Geochemistry and Health. 33, 3, p. 235-258 24 p.

Research output: Contribution to journal › Article

Humic Substances

Arsenic

humic substance

Aquifers

mobilization

21 Citations (Scopus)

An eight-coordinate vanadium thiolate complex with charge delocalization between V(V)-thiolate and V(IV)-thiyl radical forms

Chang, Y. H., Su, C. L., Wu, R. R., Liao, J. H., Liu, Y. H. & Hsu, H-F., 2011 Apr 20, In : Journal of the American Chemical Society. 133, 15, p. 5708-5711 4 p.

Research output: Contribution to journal › Article

Vanadium

Biological systems

Electronic structure

oligomycin sensitivity-conferring protein

2010

46 Citations (Scopus)

Family of V(lll)-tristhiolato complexes relevant to functional models of vanadium nitrogenase: Synthesis and electronic structure investigations by means of high-frequency and -field electron paramagnetic resonance coupled to quantum chemical computations

Ye, S., Neese, F., Ozarowsk, A., Smirnov, D., Krzystek, J., Telser, J., Liao, J. H., Hung, C. H., Chu, W. C., Tsai, Y. F., Wang, R. C., Chen, K. Y. & Hsu, H-F., 2010 Feb 1, In : Inorganic Chemistry. 49, 3, p. 977-988 12 p.

Research output: Contribution to journal › Article

Nitrogenase

vanadium

Electronic structure

Paramagnetic resonance

electron paramagnetic resonance

Tetra-butyl-ammonium bis-[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H- 4,2,1-benzothiaza-siline-1,1-diyl)dibenzene-thiol-ato]vanadium(III) acetonitrile tetrasolvate

Tsai, Y. F., Hsu, H-F., Hsu, K-F. & Wang, J. C., 2010 Jul 14, In : Acta Crystallographica Section E: Structure Reports Online. 66, 7

Research output: Contribution to journal › Article

Vanadium

Nitriles

nitriles

Acetonitrile

Ammonium Compounds

2009

12 Citations (Scopus)

Aminocarboxylate complexes of vanadium(III): Electronic structure investigation by high-frequency and -field electron paramagnetic resonance spectroscopy

Telser, J., Wu, C. C., Chen, K. Y., Hsu, H-F., Smirnov, D., Ozarowski, A. & Krzystek, J., 2009 Apr 1, In : Journal of Inorganic Biochemistry. 103, 4, p. 487-495 9 p.

Research output: Contribution to journal › Article

Vanadium

Electron Spin Resonance Spectroscopy

Electronic structure

Paramagnetic resonance

Spectrum Analysis

2008

22 Citations (Scopus)

The prophylactic protective effect of sesamol against ferric-nitrilotriacetate-induced acute renal injury in mice

Hsu, D. Z., Wan, C. H., Hsu, H-F., Lin, Y. & Liu, M-Y., 2008 Aug 1, In : Food and Chemical Toxicology. 46, 8, p. 2736-2741 6 p.

Research output: Contribution to journal › Article

Acute Kidney Injury

protective effect

kidneys

Kidney

Xanthine Oxidase

2007

7 Citations (Scopus)

Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers

Tsai, Y. F., Huang, G. S., Yang, C. I., Tsai, H-L., Liu, Y. H., Kuo, T. S. & Hsu, H-F., 2007 Dec 10, In : Inorganic Chemistry. 46, 25, p. 10467-10469 3 p.

Research output: Contribution to journal › Article

Vanadium

pyramids

vanadium

Anions

Metals

53 Citations (Scopus)

Electronic structure and FeNO conformation of nonheme iron-thiolate-NO complexes: An experimental and DFT study

Conradie, J., Quarless, D. A., Hsu, H-F., Harrop, T. C., Lippard, S. J., Koch, S. A. & Ghosh, A., 2007 Aug 29, In : Journal of the American Chemical Society. 129, 34, p. 10446-10456 11 p.

Research output: Contribution to journal › Article

Discrete Fourier transforms

Electronic structure

Conformations

Iron

Ligands

2006

32 Citations (Scopus)

Catalytic reduction of hydrazine to ammonia by a vanadium thiolate complex

Chu, W. C., Wu, C. C. & Hsu, H-F., 2006 Apr 17, In : Inorganic Chemistry. 45, 8, p. 3164-3166 3 p.

Research output: Contribution to journal › Article

hydrazine

Vanadium

hydrazines

Ammonia

vanadium

22 Citations (Scopus)

Redox chemistry in the reaction of oxovanadium(V) with thiolate-containing ligands: The isolation and characterization of non-oxo vanadium(IV) complexes containing bisulfide and thioether groups

Hsu, H-F., Su, C. L., Gopal, N. O., Wu, C. C., Chu, W. C., Tsai, Y. F., Chang, Y. H., Liu, Y. H., Kuo, T. S. & Ke, S. C., 2006 Mar 20, In : European Journal of Inorganic Chemistry. 6, p. 1161-1167 7 p.

Research output: Contribution to journal › Article

Vanadium

Sulfides

Ligands

Methylation

Geometry

2005

4 Citations (Scopus)

Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands

Hsu, H-F., Peng, W. Y., Li, Z. Y., Wu, R. R., Liao, J. H., Wang, Y., Liu, Y. H., Shieh, M. & Kuo, T. S., 2005 Mar 30, In : Inorganica Chimica Acta. 358, 6, p. 2149-2154 6 p.

Research output: Contribution to journal › Article

Molybdenum

molybdenum

Ligands

ligands

synthesis

2003

10 Citations (Scopus)

EPR spectroscopy of [Fe₂O₂(5-Et₃-TPA) ₂]³⁺: Electronic origin of the unique spin-Hamiltonian parameters of the Fe₂^III,IVO₂ diamond core

Skulan, A. J., Hanson, M. A., Hsu, H-F., Dong, Y., Que, L. & Solomon, E. I., 2003 Oct 6, In : Inorganic Chemistry. 42, 20, p. 6489-6496 8 p.

Research output: Contribution to journal › Article

Hamiltonians

Diamond

Density functional theory

Paramagnetic resonance

Orbits

31 Citations (Scopus)

Spectroscopic study of [Fe₂O₂(5-Et₃-TPA)₂]³⁺: Nature of the Fe₂O₂ diamond core and its possible relevance to high-valent binuclear non-heme enzyme intermediates

Skulan, A. J., Hanson, M. A., Hsu, H-F., Que, L. & Solomon, E. I., 2003 Jun 18, In : Journal of the American Chemical Society. 125, 24, p. 7344-7356 13 p.

Research output: Contribution to journal › Article

Diamond

Diamonds

Enzymes

Metals

Dichroism

22 Citations (Scopus)

The First Example of a Seven-Coordinate Vanadium(III) Thiolate Complex Containing the Hydrazine Molecule, an Intermediate of Nitrogen Fixation

Hsu, H-F., Chu, W. C., Hung, C. H. & Liao, J. H., 2003 Nov 17, In : Inorganic Chemistry. 42, 23, p. 7369-7371 3 p.

Research output: Contribution to journal › Article

hydrazine

Nitrogen fixation

nitrogenation

Vanadium

hydrazines

2000

99 Citations (Scopus)

Copper-induced conformational changes in the N-terminal domain of the Wilson disease copper-transporting ATPase

DiDonato, M., Hsu, H-F., Narindrasorasak, S., Que, L. & Sarkar, B., 2000 Feb 22, In : Biochemistry. 39, 7, p. 1890-1896 7 p.

Research output: Contribution to journal › Article

Hepatolenticular Degeneration

Copper

Adenosine Triphosphatases

X-Ray Absorption Spectroscopy

Binding Sites

1999

156 Citations (Scopus)

Crystal structure of a synthetic high-valent complex with an FE₂(μ- O)₂ diamond core. Implications for the core structures of methane monooxygenase intermediate Q and ribonucleotide reductase intermediate X

Hsu, H-F., Dong, Y., Shu, L., Young, V. G. & Que, L., 1999 Jun 9, In : Journal of the American Chemical Society. 121, 22, p. 5230-5237 8 p.

Research output: Contribution to journal › Article

methane monooxygenase

Ribonucleotide Reductases

Diamond

Diamonds

Methane

1997

75 Citations (Scopus)

Chemistry of iron thiolate complexes with CN^- and CO. Models for the [Fe(CO)(CN)₂ structural unit in Ni-Fe hydrogenase enzymes

Hsu, H-F. & Koch, S. A., 1997 Jan 1, In : Journal of the American Chemical Society. 119, 35, p. 8371-8372 2 p.

Research output: Contribution to journal › Article

Carbon Monoxide

Iron

Enzymes

iron hydrogenase

1996

64 Citations (Scopus)

Nickel(II) thiolate complex with carbon monoxide and its Fe(II) analog: Synthetic models for CO adducts of nickel-iron-containing enzymes

Nguyen, D. H., Hsu, H-F., Millar, M., Koch, S. A., Achim, C., Bominaar, E. L. & Münck, E., 1996 Sep 18, In : Journal of the American Chemical Society. 118, 37, p. 8963-8964 2 p.

Research output: Contribution to journal › Article

Carbon Monoxide

Nickel

Iron

Enzymes