Abstract
Cadmium sulfide (CdS) was in situ synthesized onto mesoporous TiO 2 films and used as a sensitizer to fabricate a photoelectrode for hydrogen generation in visible light. The incorporation of CdS extends the optical absorption threshold of a TiO2 electrode to visible light, enhancing the visible-light-induced photocurrent. A maximum photoconversion efficiency of 3.67% was achieved for this CdS-sensitized TiO2 electrode under visible light illumination of 100 mW cm-2. The hydrogen generation rate obtained at conditions of maximum efficiency is 95.5 μmol cm-2 h-1. To the best of our knowledge, the hydrogen generation rate is the highest among those reported for a photoelectrochemical cell under the illumination of visible light.
Original language | English |
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Article number | 125704 |
Journal | Nanotechnology |
Volume | 19 |
Issue number | 12 |
DOIs | |
Publication status | Published - 2008 Mar 26 |
All Science Journal Classification (ASJC) codes
- Bioengineering
- General Chemistry
- General Materials Science
- Mechanics of Materials
- Mechanical Engineering
- Electrical and Electronic Engineering