TY - JOUR
T1 - A criterion for proper cosolvents used for ionic liquids
T2 - The Lewis acidic and basic dual nature of propylene carbonate
AU - Hsu, Wen Yi
AU - Tai, Chia Cheng
AU - Su, Wei Lin
AU - Chang, Chia Hang
AU - Wang, Shao Pin
AU - Sun, I. Wen
N1 - Funding Information:
We thank the National Cheng Kung University (NCKU) and the National Science Council (Grant No.: NSC 95-2113-M-006-016) for financial support. Ms. J.-J. Wu at the Instrument Centre (NMR Division) of NCKU is highly appreciated for her assistance in NMR diffusion experiments.
PY - 2008/4/1
Y1 - 2008/4/1
N2 - Probe of the Lewis acidic property of propylene carbonate (PC) has been initiated by temperature-dependent 19F chemical shifts recorded for 1-butyl-3-methylimidazolium hexafluorophosphate/PC (BMIPF6/PC) mixtures. Investigation of hyperconjugative interactions by natural bond orbital method reveals the trend of electron-accepting capabilities from PF6- anion, PC > dimethyl sulfoxide (DMSO) > N,N-dimethyl formamide (DMF) > acetonitrile (AN). Comparison of solvent-induced ionic association of BMIPF6 in the four basic aprotic organic solvents, made by monitoring concentration- and temperature-dependent-ratios of solvent diffusion coefficients to BMI+-containing components, Dsol/DBMI, shows that the extent of original ionic association can be reduced by solvent dilution in the same decreasing order, PC ∼ DMSO > DMF > AN. In DMF and AN, two basic solvents having similar dielectric constants, the greater Lewis acid of DMF accounts for its better ability to dissociate aggregates of BMIPF6. By replacing ethanol with 2,2,2-trifluoroethanol (TFE), the poor miscibility of BMIPF6 with ethanol can be greatly enhanced due to the CF3 group, capable of adapting electron density from anions via hyperconjugative interactions. In BMIPF6/TFE mixtures, values of DTFEF / DPF6 measured on 19F resonances show larger aggregates than DTFEH / DBMImeasured on 1H resonances, indicating charged clusters prefer anionic to cationic states. This observation can be explained by varying ionic states concerning with unbalanced charged aggregates between positive and negative ones.
AB - Probe of the Lewis acidic property of propylene carbonate (PC) has been initiated by temperature-dependent 19F chemical shifts recorded for 1-butyl-3-methylimidazolium hexafluorophosphate/PC (BMIPF6/PC) mixtures. Investigation of hyperconjugative interactions by natural bond orbital method reveals the trend of electron-accepting capabilities from PF6- anion, PC > dimethyl sulfoxide (DMSO) > N,N-dimethyl formamide (DMF) > acetonitrile (AN). Comparison of solvent-induced ionic association of BMIPF6 in the four basic aprotic organic solvents, made by monitoring concentration- and temperature-dependent-ratios of solvent diffusion coefficients to BMI+-containing components, Dsol/DBMI, shows that the extent of original ionic association can be reduced by solvent dilution in the same decreasing order, PC ∼ DMSO > DMF > AN. In DMF and AN, two basic solvents having similar dielectric constants, the greater Lewis acid of DMF accounts for its better ability to dissociate aggregates of BMIPF6. By replacing ethanol with 2,2,2-trifluoroethanol (TFE), the poor miscibility of BMIPF6 with ethanol can be greatly enhanced due to the CF3 group, capable of adapting electron density from anions via hyperconjugative interactions. In BMIPF6/TFE mixtures, values of DTFEF / DPF6 measured on 19F resonances show larger aggregates than DTFEH / DBMImeasured on 1H resonances, indicating charged clusters prefer anionic to cationic states. This observation can be explained by varying ionic states concerning with unbalanced charged aggregates between positive and negative ones.
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U2 - 10.1016/j.ica.2007.08.011
DO - 10.1016/j.ica.2007.08.011
M3 - Article
AN - SCOPUS:39549095602
SN - 0020-1693
VL - 361
SP - 1281
EP - 1290
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 5
ER -