A facile high-yield solvothermal route to tin phosphide Sn4P3

Kirill A. Kovnir, Yury V. Kolen'ko, Sugata Ray, Jinwang Li, Tomoaki Watanabe, Mitsuru Itoh, Masahiro Yoshimura, Andrei V. Shevelkov

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44 Citations (Scopus)

Abstract

An effective method of synthesis of tin phosphide Sn4P3 starting from metallic tin and amorphous red phosphorus by a low-temperature (200 °C) solvothermal reaction in ethylenediamine is offered. The key parameters of this process - duration, temperature, and the ratio of initial components (Sn/P) are studied. The structure, phase composition, and morphology of the products are investigated using powder X-ray diffraction and scanning electron microscopy. Different synthetic ways for tin phosphide are discussed and compared with the proposed one. The mechanism of solvothermal preparation of tin phosphide in ethylenediamine is discussed. It is shown that the proposed solvothermal method opens up the possibility of preparing other metal-rich phosphides.

Original languageEnglish
Pages (from-to)3756-3762
Number of pages7
JournalJournal of Solid State Chemistry
Volume179
Issue number12
DOIs
Publication statusPublished - 2006 Dec

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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