A generalized theory explains the anomalous suns- VOC response of si heterojunction solar cells

Raghu Vamsi Krishna Chavali, Jian V. Li, Corsin Battaglia, Stefaan De Wolf, Jeffery Lynn Gray, Muhammad Ashraful Alam

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Suns-VOC measurements exclude parasitic series resistance effects and are, therefore, frequently used to study the intrinsic potential of a given photovoltaic technology. However, when applied to a-Si/c-Si heterojunction (SHJ) solar cells, the Suns- Voc curves often feature a peculiar turnaround at high illumination intensities. Generally, this turn-around is attributed to extrinsic Schottky contacts that should disappear with process improvement. In this paper, we demonstrate that this voltage turnaround may be an intrinsic feature of SHJ solar cells, arising from the heterojunction (HJ), as well as its associated carrier-transport barriers, inherent to SHJ devices. We use numerical simulations to explore the full current-voltage (J-V) characteristics under different illumination and ambient temperature conditions. Using these characteristics, we establish the voltage and illumination-intensity bias, as well as temperature conditions necessary to observe the voltage turnaround in these cells. We validate our turnaround hypothesis using an extensive set of experiments on a high-efficiency SHJ solar cell and a molybdenum oxide (MoOx) based hole collector HJ solar cell. Our work consolidates Suns- $V{{\rm{oc}}}$ as a powerful characterization tool for extracting the cell parameters that limit efficiency in HJ devices.

Original languageEnglish
Article number7756368
Pages (from-to)169-176
Number of pages8
JournalIEEE Journal of Photovoltaics
Volume7
Issue number1
DOIs
Publication statusPublished - 2017 Jan

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Electrical and Electronic Engineering

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