A novel composite gel polymer electrolyte for rechargeable lithium batteries

Han Hsin Kuo; Wei Chih Chen; Ten Chin Wen; A. Gopalan

A novel composite gel polymer electrolyte for rechargeable lithium batteries

Han Hsin Kuo, Wei Chih Chen, Ten Chin Wen, A. Gopalan

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Composite polymer electrolyte (PE) films comprising thermoplastic polyurethane (TPU) and polyacrylonitrile (PAN) (denoted as TPU-PAN) were prepared by two different processes. The preparation of the TPU-PAN gel PE was more convenient than the traditional way of making PAN based electrolyte. The TPU-PAN composite possessed good mechanical properties. The TPU-PAN based gel PE showed high conductivity at room temperature. The existence of PAN in the composite improved the thermal stability. The lithium plating-stripping process was a reversible and implied better electrochemical stability in the working voltage range. The Li/PE (TPU-PAN)/LiCoO₂ cell was successfully constructed and the performance was assessed. The formation of passive layer at Li/PE interface influenced the charge-discharge characteristics.

Original language	English
Pages (from-to)	27-33
Number of pages	7
Journal	Journal of Power Sources
Volume	110
Issue number	2
Publication status	Published - 2002 Aug 22

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Cite this

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title = "A novel composite gel polymer electrolyte for rechargeable lithium batteries",

abstract = "Composite polymer electrolyte (PE) films comprising thermoplastic polyurethane (TPU) and polyacrylonitrile (PAN) (denoted as TPU-PAN) were prepared by two different processes. The preparation of the TPU-PAN gel PE was more convenient than the traditional way of making PAN based electrolyte. The TPU-PAN composite possessed good mechanical properties. The TPU-PAN based gel PE showed high conductivity at room temperature. The existence of PAN in the composite improved the thermal stability. The lithium plating-stripping process was a reversible and implied better electrochemical stability in the working voltage range. The Li/PE (TPU-PAN)/LiCoO2 cell was successfully constructed and the performance was assessed. The formation of passive layer at Li/PE interface influenced the charge-discharge characteristics.",

author = "Kuo, {Han Hsin} and Chen, {Wei Chih} and Wen, {Ten Chin} and A. Gopalan",

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T1 - A novel composite gel polymer electrolyte for rechargeable lithium batteries

AU - Kuo, Han Hsin

AU - Chen, Wei Chih

AU - Wen, Ten Chin

AU - Gopalan, A.

N1 - Funding Information: The authors are grateful to the National Science Council in Taiwan for its financial support through NSC 89-2622-E-006-001.

PY - 2002/8/22

Y1 - 2002/8/22

N2 - Composite polymer electrolyte (PE) films comprising thermoplastic polyurethane (TPU) and polyacrylonitrile (PAN) (denoted as TPU-PAN) were prepared by two different processes. The preparation of the TPU-PAN gel PE was more convenient than the traditional way of making PAN based electrolyte. The TPU-PAN composite possessed good mechanical properties. The TPU-PAN based gel PE showed high conductivity at room temperature. The existence of PAN in the composite improved the thermal stability. The lithium plating-stripping process was a reversible and implied better electrochemical stability in the working voltage range. The Li/PE (TPU-PAN)/LiCoO2 cell was successfully constructed and the performance was assessed. The formation of passive layer at Li/PE interface influenced the charge-discharge characteristics.

AB - Composite polymer electrolyte (PE) films comprising thermoplastic polyurethane (TPU) and polyacrylonitrile (PAN) (denoted as TPU-PAN) were prepared by two different processes. The preparation of the TPU-PAN gel PE was more convenient than the traditional way of making PAN based electrolyte. The TPU-PAN composite possessed good mechanical properties. The TPU-PAN based gel PE showed high conductivity at room temperature. The existence of PAN in the composite improved the thermal stability. The lithium plating-stripping process was a reversible and implied better electrochemical stability in the working voltage range. The Li/PE (TPU-PAN)/LiCoO2 cell was successfully constructed and the performance was assessed. The formation of passive layer at Li/PE interface influenced the charge-discharge characteristics.

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A novel composite gel polymer electrolyte for rechargeable lithium batteries

Abstract

All Science Journal Classification (ASJC) codes

UN SDGs

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