A novel lithium single ion based polyurethane electrolyte for light-emitting electrochemical cell

Hsing Lung Wang; A. Gopalan; Ten Chin Wen

doi:10.1016/S0254-0584(03)00363-8

A novel lithium single ion based polyurethane electrolyte for light-emitting electrochemical cell

Hsing Lung Wang, A. Gopalan, Ten Chin Wen

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Light-emitting electrochemical cell (LEC) was fabricated with poly(para-phenylene vinylene) (PPV), as light-emitting material and lithium ion conducting waterborne polyurethane ionomer (WPUI) as solid electrolyte. We report the current-voltage-light output characteristics, morphology and ion transport behavior of the device. Cyclic voltammetry (CV) has been performed to reveal the ionic and electronic contributions of current. The threshold voltage for electrochemical doping of PPV in ITO/WPUI + PPV/Al device was evaluated. Scanning force micrograph of blend of WPUI with PPV is presented. The alternating current (ac) impedance analysis was made in the frequency range 1 MHz to 1 Hz to bring out the impedance changes with applied (bias) dc potentials. Results demonstrate that WPUI can be used as a single component electrolyte in LEC fabrication in contrast to two components (polymer and lithium salt) used earlier.

Original language	English
Pages (from-to)	793-800
Number of pages	8
Journal	Materials Chemistry and Physics
Volume	82
Issue number	3
DOIs	https://doi.org/10.1016/S0254-0584(03)00363-8
Publication status	Published - 2003 Dec 20

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics

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title = "A novel lithium single ion based polyurethane electrolyte for light-emitting electrochemical cell",

abstract = "Light-emitting electrochemical cell (LEC) was fabricated with poly(para-phenylene vinylene) (PPV), as light-emitting material and lithium ion conducting waterborne polyurethane ionomer (WPUI) as solid electrolyte. We report the current-voltage-light output characteristics, morphology and ion transport behavior of the device. Cyclic voltammetry (CV) has been performed to reveal the ionic and electronic contributions of current. The threshold voltage for electrochemical doping of PPV in ITO/WPUI + PPV/Al device was evaluated. Scanning force micrograph of blend of WPUI with PPV is presented. The alternating current (ac) impedance analysis was made in the frequency range 1 MHz to 1 Hz to bring out the impedance changes with applied (bias) dc potentials. Results demonstrate that WPUI can be used as a single component electrolyte in LEC fabrication in contrast to two components (polymer and lithium salt) used earlier.",

author = "Wang, {Hsing Lung} and A. Gopalan and Wen, {Ten Chin}",

note = "Funding Information: The financial support of this work by the National Science Council of Taiwan under NSC91-2214-E-006-010 is gratefully acknowledged.",

year = "2003",

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doi = "10.1016/S0254-0584(03)00363-8",

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T1 - A novel lithium single ion based polyurethane electrolyte for light-emitting electrochemical cell

AU - Wang, Hsing Lung

AU - Gopalan, A.

AU - Wen, Ten Chin

N1 - Funding Information: The financial support of this work by the National Science Council of Taiwan under NSC91-2214-E-006-010 is gratefully acknowledged.

PY - 2003/12/20

Y1 - 2003/12/20

N2 - Light-emitting electrochemical cell (LEC) was fabricated with poly(para-phenylene vinylene) (PPV), as light-emitting material and lithium ion conducting waterborne polyurethane ionomer (WPUI) as solid electrolyte. We report the current-voltage-light output characteristics, morphology and ion transport behavior of the device. Cyclic voltammetry (CV) has been performed to reveal the ionic and electronic contributions of current. The threshold voltage for electrochemical doping of PPV in ITO/WPUI + PPV/Al device was evaluated. Scanning force micrograph of blend of WPUI with PPV is presented. The alternating current (ac) impedance analysis was made in the frequency range 1 MHz to 1 Hz to bring out the impedance changes with applied (bias) dc potentials. Results demonstrate that WPUI can be used as a single component electrolyte in LEC fabrication in contrast to two components (polymer and lithium salt) used earlier.

AB - Light-emitting electrochemical cell (LEC) was fabricated with poly(para-phenylene vinylene) (PPV), as light-emitting material and lithium ion conducting waterborne polyurethane ionomer (WPUI) as solid electrolyte. We report the current-voltage-light output characteristics, morphology and ion transport behavior of the device. Cyclic voltammetry (CV) has been performed to reveal the ionic and electronic contributions of current. The threshold voltage for electrochemical doping of PPV in ITO/WPUI + PPV/Al device was evaluated. Scanning force micrograph of blend of WPUI with PPV is presented. The alternating current (ac) impedance analysis was made in the frequency range 1 MHz to 1 Hz to bring out the impedance changes with applied (bias) dc potentials. Results demonstrate that WPUI can be used as a single component electrolyte in LEC fabrication in contrast to two components (polymer and lithium salt) used earlier.

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U2 - 10.1016/S0254-0584(03)00363-8

DO - 10.1016/S0254-0584(03)00363-8

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SN - 0254-0584

VL - 82

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EP - 800

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

IS - 3

ER -

A novel lithium single ion based polyurethane electrolyte for light-emitting electrochemical cell

Abstract

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