Absorption spectra of trilayer rhombohedral graphite are studied with the tight-binding model. The interlayer interactions cause a tiny energy gap and band-edge states in electronic structures. The band-edge states exhibit logarithmic divergences and discontinuities in the density of states. The frequencies of the absorption peaks correspond to the vertical transition energies of the band-edge states. Optical spectra of trilayer simple hexagonal and orthorhombic graphites are also investigated. The stacking effects on the density of states and absorption spectra are presented and discussed in detail.
All Science Journal Classification (ASJC) codes
- Physics and Astronomy (miscellaneous)