Activation of dichloromethane by a V(iii) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate

Tzu Tso Chen, Yu Sen Chen, Ya Ho Chang, Jung Ching Wang, Yi Fang Tsai, Gene Hsiang Lee, Tin Shen Kuo, Hua Fen Hsu

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

Original languageEnglish
Pages (from-to)1109-1111
Number of pages3
JournalChemical Communications
Volume49
Issue number11
DOIs
Publication statusPublished - 2013 Feb 4

Fingerprint

Methylene Chloride
Dichloromethane
Reaction products
Sulfur
Transition metals
Chemical activation
Ligands

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Chen, Tzu Tso ; Chen, Yu Sen ; Chang, Ya Ho ; Wang, Jung Ching ; Tsai, Yi Fang ; Lee, Gene Hsiang ; Kuo, Tin Shen ; Hsu, Hua Fen. / Activation of dichloromethane by a V(iii) thiolate complex : An example of S-based nucleophilic reactivity in an early transition metal thiolate. In: Chemical Communications. 2013 ; Vol. 49, No. 11. pp. 1109-1111.
@article{1f8f81a424e94752bcb7f5ca613e71f6,
title = "Activation of dichloromethane by a V(iii) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate",
abstract = "A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.",
author = "Chen, {Tzu Tso} and Chen, {Yu Sen} and Chang, {Ya Ho} and Wang, {Jung Ching} and Tsai, {Yi Fang} and Lee, {Gene Hsiang} and Kuo, {Tin Shen} and Hsu, {Hua Fen}",
year = "2013",
month = "2",
day = "4",
doi = "10.1039/c2cc37801a",
language = "English",
volume = "49",
pages = "1109--1111",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "11",

}

Activation of dichloromethane by a V(iii) thiolate complex : An example of S-based nucleophilic reactivity in an early transition metal thiolate. / Chen, Tzu Tso; Chen, Yu Sen; Chang, Ya Ho; Wang, Jung Ching; Tsai, Yi Fang; Lee, Gene Hsiang; Kuo, Tin Shen; Hsu, Hua Fen.

In: Chemical Communications, Vol. 49, No. 11, 04.02.2013, p. 1109-1111.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Activation of dichloromethane by a V(iii) thiolate complex

T2 - An example of S-based nucleophilic reactivity in an early transition metal thiolate

AU - Chen, Tzu Tso

AU - Chen, Yu Sen

AU - Chang, Ya Ho

AU - Wang, Jung Ching

AU - Tsai, Yi Fang

AU - Lee, Gene Hsiang

AU - Kuo, Tin Shen

AU - Hsu, Hua Fen

PY - 2013/2/4

Y1 - 2013/2/4

N2 - A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

AB - A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

UR - http://www.scopus.com/inward/record.url?scp=84872194886&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84872194886&partnerID=8YFLogxK

U2 - 10.1039/c2cc37801a

DO - 10.1039/c2cc37801a

M3 - Article

C2 - 23282950

AN - SCOPUS:84872194886

VL - 49

SP - 1109

EP - 1111

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 11

ER -