Activation of dichloromethane by a V(III) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate

Tzu Tso Chen, Yu Sen Chen, Ya Ho Chang, Jung Ching Wang, Yi Fang Tsai, Gene Hsiang Lee, Tin Shen Kuo, Hua Fen Hsu

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

Original languageEnglish
Pages (from-to)1109-1111
Number of pages3
JournalChemical Communications
Volume49
Issue number11
DOIs
Publication statusPublished - 2013 Jan 10

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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