Activation of dichloromethane by a V(iii) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate

Tzu Tso Chen, Yu Sen Chen, Ya Ho Chang, Jung Ching Wang, Yi Fang Tsai, Gene Hsiang Lee, Tin Shen Kuo, Hua Fen Hsu

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

Original languageEnglish
Pages (from-to)1109-1111
Number of pages3
JournalChemical Communications
Volume49
Issue number11
DOIs
Publication statusPublished - 2013 Feb 4

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Methylene Chloride
Dichloromethane
Reaction products
Sulfur
Transition metals
Chemical activation
Ligands

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Chen, Tzu Tso ; Chen, Yu Sen ; Chang, Ya Ho ; Wang, Jung Ching ; Tsai, Yi Fang ; Lee, Gene Hsiang ; Kuo, Tin Shen ; Hsu, Hua Fen. / Activation of dichloromethane by a V(iii) thiolate complex : An example of S-based nucleophilic reactivity in an early transition metal thiolate. In: Chemical Communications. 2013 ; Vol. 49, No. 11. pp. 1109-1111.
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abstract = "A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.",
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Chen, TT, Chen, YS, Chang, YH, Wang, JC, Tsai, YF, Lee, GH, Kuo, TS & Hsu, HF 2013, 'Activation of dichloromethane by a V(iii) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate', Chemical Communications, vol. 49, no. 11, pp. 1109-1111. https://doi.org/10.1039/c2cc37801a

Activation of dichloromethane by a V(iii) thiolate complex : An example of S-based nucleophilic reactivity in an early transition metal thiolate. / Chen, Tzu Tso; Chen, Yu Sen; Chang, Ya Ho; Wang, Jung Ching; Tsai, Yi Fang; Lee, Gene Hsiang; Kuo, Tin Shen; Hsu, Hua Fen.

In: Chemical Communications, Vol. 49, No. 11, 04.02.2013, p. 1109-1111.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Activation of dichloromethane by a V(iii) thiolate complex

T2 - An example of S-based nucleophilic reactivity in an early transition metal thiolate

AU - Chen, Tzu Tso

AU - Chen, Yu Sen

AU - Chang, Ya Ho

AU - Wang, Jung Ching

AU - Tsai, Yi Fang

AU - Lee, Gene Hsiang

AU - Kuo, Tin Shen

AU - Hsu, Hua Fen

PY - 2013/2/4

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N2 - A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

AB - A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

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Chen TT, Chen YS, Chang YH, Wang JC, Tsai YF, Lee GH et al. Activation of dichloromethane by a V(iii) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate. Chemical Communications. 2013 Feb 4;49(11):1109-1111. https://doi.org/10.1039/c2cc37801a

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