Abstract
A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.
Original language | English |
---|---|
Pages (from-to) | 1109-1111 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 49 |
Issue number | 11 |
DOIs | |
Publication status | Published - 2013 Jan 10 |
All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry