Activation of dichloromethane by a V(III) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate

Tzu Tso Chen; Yu Sen Chen; Ya Ho Chang; Jung Ching Wang; Yi Fang Tsai; Gene Hsiang Lee; Tin Shen Kuo; Hua Fen Hsu

doi:10.1039/c2cc37801a

Activation of dichloromethane by a V(III) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate

Tzu Tso Chen, Yu Sen Chen, Ya Ho Chang, Jung Ching Wang, Yi Fang Tsai, Gene Hsiang Lee, Tin Shen Kuo, Hua Fen Hsu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A V^III thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a V^III-Cl species (major one) and a V^IV binding to a CH₂ containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

Original language	English
Pages (from-to)	1109-1111
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	11
DOIs	https://doi.org/10.1039/c2cc37801a
Publication status	Published - 2013 Jan 10

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc37801a

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title = "Activation of dichloromethane by a V(III) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate",

abstract = "A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.",

author = "Chen, {Tzu Tso} and Chen, {Yu Sen} and Chang, {Ya Ho} and Wang, {Jung Ching} and Tsai, {Yi Fang} and Lee, {Gene Hsiang} and Kuo, {Tin Shen} and Hsu, {Hua Fen}",

year = "2013",

month = jan,

day = "10",

doi = "10.1039/c2cc37801a",

language = "English",

volume = "49",

pages = "1109--1111",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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Activation of dichloromethane by a V(III) thiolate complex : An example of S-based nucleophilic reactivity in an early transition metal thiolate. / Chen, Tzu Tso; Chen, Yu Sen; Chang, Ya Ho; Wang, Jung Ching; Tsai, Yi Fang; Lee, Gene Hsiang; Kuo, Tin Shen; Hsu, Hua Fen.

In: Chemical Communications, Vol. 49, No. 11, 10.01.2013, p. 1109-1111.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Activation of dichloromethane by a V(III) thiolate complex

T2 - An example of S-based nucleophilic reactivity in an early transition metal thiolate

AU - Chen, Tzu Tso

AU - Chen, Yu Sen

AU - Chang, Ya Ho

AU - Wang, Jung Ching

AU - Tsai, Yi Fang

AU - Lee, Gene Hsiang

AU - Kuo, Tin Shen

AU - Hsu, Hua Fen

PY - 2013/1/10

Y1 - 2013/1/10

N2 - A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

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Activation of dichloromethane by a V(III) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate

Abstract

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