Amide-Functionalized Small Molecules as Solution-Processed Electron Injection Layers in Highly Efficient Polymer Light-Emitting Diodes

Chen Hao Wu, Kai Wei Tsai, Wei Jhe Huang, Chen Yu Wu, Tsan Yao Chen, Tzung Fang Guo, Yao Jane Hsu, Ten Chin Wen

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Abstract

An efficient polymer light-emitting diode (PLED) is demonstrated using the solution-processed octadecanamide (ODAD) as an electron injection layer (EIL). The ability for the EIL of ODAD to lower the electron injection barrier is systematically investigated by the analysis of structural analogs, photovoltaic measurements, X-ray photoelectron spectroscopy (XPS), and ultraviolet photoelectron spectroscopy (UPS). Devices with ODAD/Al and 2-phenylacetamide/Al cathodes show the higher luminance efficiency (8.5 and 11.0 cd A-1) than that with the Ca/Al cathode (5.9 cd A-1). On the contrary, the device with the octadecylamine/Al cathode shows the performance similar to that of the device with the Al cathode. It correlates the amide functional group with the enhanced electron injection. The corresponding photovoltaic measurements suggest the amide functional group be essential to decrease the work function (WF) of Al. XPS and UPS verify the mechanism for lowering electron injection barrier: the amide functional group forms the C-O-Al complex at the ODAD/Al interface to create the interfacial dipole for decreasing the WF of Al. This is the first demonstration that efficient PLEDs are achieved using amide-functionalized small molecules as EILs. The work here paves the way for developing interfacial materials with the amide functional group to achieve efficient organic/polymer optoelectronics. Solution-processed octadecanamide and 2-phenylacetamide are used as electron injection layers to fabricate highly efficient polymer light-emitting diodes. An amide functional group coupled with Al forms the COAl complex, leading to the decreased Al work function which ensures a remarkable electron injection. It paves the way for developing interfacial materials with an amide functional group to achieve high-performance organic/polymer optoelectronics.

Original languageEnglish
Article number1500621
JournalAdvanced Materials Interfaces
Volume3
Issue number6
DOIs
Publication statusPublished - 2016 Mar 23

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All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering

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