TY - JOUR
T1 - An experimental and theoretical investigation on structure-property correlation of Cu2Mn1Al1−xGax full-Heusler alloy
AU - Mishra, Shashank Shekhar
AU - Bajpai, Anurag
AU - Yadav, Thakur Prasad
AU - Yadav, Ram Manohar
AU - Puthirath, Anand B.
AU - Deng, Liangzi
AU - Adnani, Moein
AU - Chu, Ching Wu
AU - Vajtai, Robert
AU - Ajayan, Pulickel M.
AU - Biswas, Krishanu
AU - Mukhopadhyay, Nilay Krishna
N1 - Publisher Copyright:
© 2021 Elsevier B.V.
PY - 2022/3/25
Y1 - 2022/3/25
N2 - The present study reports the evolution of microstructure and magnetic properties of Cu2MnAl1−xGax Heusler alloys. The L21 phase, which remained stable up to a Ga substitution of x = 0.3, transformed into mixed phases, i.e., hexagonal close packed (HCP) and complex cubic structure (CCS) on further addition of Ga. The non-monotonic increase in the lattice constant indicates that some amount of Ga retains its monovalent state. The magnetic phase showed a transition from ferromagnetic to paramagnetic state with increasing Ga concentration. The re-entrant temperature (TR) decreased from 8.2 K to 5.2 K as Ga content increased from 5 at% to 10 at%. The strength of magnetic exchange-coupling also reduced with an increase in Ga content. Gaussian process regression (GPR) was used to estimate the lattice parameter using the ionic radii and Pauling electronegativity of the constituents. The modeling approach showed high accuracy and stability, providing new insights into future alloy development.
AB - The present study reports the evolution of microstructure and magnetic properties of Cu2MnAl1−xGax Heusler alloys. The L21 phase, which remained stable up to a Ga substitution of x = 0.3, transformed into mixed phases, i.e., hexagonal close packed (HCP) and complex cubic structure (CCS) on further addition of Ga. The non-monotonic increase in the lattice constant indicates that some amount of Ga retains its monovalent state. The magnetic phase showed a transition from ferromagnetic to paramagnetic state with increasing Ga concentration. The re-entrant temperature (TR) decreased from 8.2 K to 5.2 K as Ga content increased from 5 at% to 10 at%. The strength of magnetic exchange-coupling also reduced with an increase in Ga content. Gaussian process regression (GPR) was used to estimate the lattice parameter using the ionic radii and Pauling electronegativity of the constituents. The modeling approach showed high accuracy and stability, providing new insights into future alloy development.
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U2 - 10.1016/j.jallcom.2021.162865
DO - 10.1016/j.jallcom.2021.162865
M3 - Article
AN - SCOPUS:85120488224
SN - 0925-8388
VL - 898
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
M1 - 162865
ER -