An iridium-decorated metal–organic framework for electrocatalytic oxidation of nitrite

Tzu En Chang, Cheng Hsun Chuang, Chung Wei Kung

Research output: Contribution to journalArticlepeer-review

Abstract

Spatially dispersed redox-active iridium sites are immobilized throughout the porous framework of a zirconium-based metal–organic framework (MOF), UiO-66, to enable charge hopping in the MOF. The resulting iridium sites within UiO-66 not only permit redox hopping-based electron transport within the MOF in aqueous electrolytes, but also exhibit electrocatalytic activity for the oxidation of nitrite. The pH of the electrolyte for this electrocatalysis is optimized, and the electrocatalytic mechanism occurring on the Ir-decorated UiO-66 thin films is investigated. The material is further applied for amperometric nitrite sensing in aqueous solutions. Owing to its high porosity, the Ir-decorated UiO-66 achieves a good sensitivity (168.8 μA/mM-cm2) for detecting nitrite with a low limit of detection (0.41 μM).

Original languageEnglish
Article number106899
JournalElectrochemistry Communications
Volume122
DOIs
Publication statusPublished - 2021 Jan

All Science Journal Classification (ASJC) codes

  • Electrochemistry

Fingerprint Dive into the research topics of 'An iridium-decorated metal–organic framework for electrocatalytic oxidation of nitrite'. Together they form a unique fingerprint.

Cite this