Application of samaria doped sculptured ceria/La1-xSr xCo1-yFeyO3-δ in cathode of SOFCs at intermediate temperature

Ming Hsiu Wu; Jow Lay Huang; Kuan Zong Fung; Ding Fwu Lii

doi:10.1016/j.vacuum.2013.07.031

Application of samaria doped sculptured ceria/La_1-xSr _xCo_1-yFe_yO_3-δ in cathode of SOFCs at intermediate temperature

Ming Hsiu Wu, Jow Lay Huang, Kuan Zong Fung, Ding Fwu Lii

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Samaria-doped ceria (SDC)/La_1-xSr_xCo _1-yFe_yO_3-δ (LSCF) and yttria-stabilized zirconia (YSZ)/Ni were prepared as the cathode and anode of a solid oxide fuel cell (SOFC), respectively, using glancing angle deposition (GLAD) in electron beam physical vapor deposition. Fuel cell current-voltage measurements and electrochemical impedance spectroscopy were performed at 600 C. The investigations of the crystalline structures were examined using X-ray diffraction and transmission electron microscopy (TEM). A fluorite structure of SDC and the rhombohedral phase of the LSCF film were obtained. TEM images show that the diameter of each SDC single-crystalline column was approximately 50 nm. The results of scanning electron microscopy and electrochemical impedance spectroscopy indicate that high-density triple phase boundary (TPB) in the cathode enhances the performance of SOFC.

Original language	English
Pages (from-to)	57-62
Number of pages	6
Journal	Vacuum
Volume	101
DOIs	https://doi.org/10.1016/j.vacuum.2013.07.031
Publication status	Published - 2014

All Science Journal Classification (ASJC) codes

Instrumentation
Condensed Matter Physics
Surfaces, Coatings and Films

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10.1016/j.vacuum.2013.07.031

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title = "Application of samaria doped sculptured ceria/La1-xSr xCo1-yFeyO3-δ in cathode of SOFCs at intermediate temperature",

abstract = "Samaria-doped ceria (SDC)/La1-xSrxCo 1-yFeyO3-δ (LSCF) and yttria-stabilized zirconia (YSZ)/Ni were prepared as the cathode and anode of a solid oxide fuel cell (SOFC), respectively, using glancing angle deposition (GLAD) in electron beam physical vapor deposition. Fuel cell current-voltage measurements and electrochemical impedance spectroscopy were performed at 600 C. The investigations of the crystalline structures were examined using X-ray diffraction and transmission electron microscopy (TEM). A fluorite structure of SDC and the rhombohedral phase of the LSCF film were obtained. TEM images show that the diameter of each SDC single-crystalline column was approximately 50 nm. The results of scanning electron microscopy and electrochemical impedance spectroscopy indicate that high-density triple phase boundary (TPB) in the cathode enhances the performance of SOFC.",

author = "Wu, {Ming Hsiu} and Huang, {Jow Lay} and Fung, {Kuan Zong} and Lii, {Ding Fwu}",

note = "Funding Information: The authors are grateful for the support by National Cheng Kung University Research Center for Energy Technology and Strategy and the program under grant No. NSC 101-2221-E-006 -129 from the National Science Council of Taiwan .",

year = "2014",

doi = "10.1016/j.vacuum.2013.07.031",

language = "English",

volume = "101",

pages = "57--62",

journal = "Vacuum",

issn = "0042-207X",

publisher = "Elsevier Limited",

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T1 - Application of samaria doped sculptured ceria/La1-xSr xCo1-yFeyO3-δ in cathode of SOFCs at intermediate temperature

AU - Wu, Ming Hsiu

AU - Huang, Jow Lay

AU - Fung, Kuan Zong

AU - Lii, Ding Fwu

N1 - Funding Information: The authors are grateful for the support by National Cheng Kung University Research Center for Energy Technology and Strategy and the program under grant No. NSC 101-2221-E-006 -129 from the National Science Council of Taiwan .

PY - 2014

Y1 - 2014

N2 - Samaria-doped ceria (SDC)/La1-xSrxCo 1-yFeyO3-δ (LSCF) and yttria-stabilized zirconia (YSZ)/Ni were prepared as the cathode and anode of a solid oxide fuel cell (SOFC), respectively, using glancing angle deposition (GLAD) in electron beam physical vapor deposition. Fuel cell current-voltage measurements and electrochemical impedance spectroscopy were performed at 600 C. The investigations of the crystalline structures were examined using X-ray diffraction and transmission electron microscopy (TEM). A fluorite structure of SDC and the rhombohedral phase of the LSCF film were obtained. TEM images show that the diameter of each SDC single-crystalline column was approximately 50 nm. The results of scanning electron microscopy and electrochemical impedance spectroscopy indicate that high-density triple phase boundary (TPB) in the cathode enhances the performance of SOFC.

AB - Samaria-doped ceria (SDC)/La1-xSrxCo 1-yFeyO3-δ (LSCF) and yttria-stabilized zirconia (YSZ)/Ni were prepared as the cathode and anode of a solid oxide fuel cell (SOFC), respectively, using glancing angle deposition (GLAD) in electron beam physical vapor deposition. Fuel cell current-voltage measurements and electrochemical impedance spectroscopy were performed at 600 C. The investigations of the crystalline structures were examined using X-ray diffraction and transmission electron microscopy (TEM). A fluorite structure of SDC and the rhombohedral phase of the LSCF film were obtained. TEM images show that the diameter of each SDC single-crystalline column was approximately 50 nm. The results of scanning electron microscopy and electrochemical impedance spectroscopy indicate that high-density triple phase boundary (TPB) in the cathode enhances the performance of SOFC.

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U2 - 10.1016/j.vacuum.2013.07.031

DO - 10.1016/j.vacuum.2013.07.031

M3 - Article

AN - SCOPUS:84883177333

SN - 0042-207X

VL - 101

SP - 57

EP - 62

JO - Vacuum

JF - Vacuum

ER -

Application of samaria doped sculptured ceria/La_1-xSr _xCo_1-yFe_yO_3-δ in cathode of SOFCs at intermediate temperature

Abstract

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