Atmospheric air plasma treated SnS films

An efficient electrocatalyst for HER

Po Chia Huang, Sanjaya Brahma, Po Yen Liu, Jow-Lay Huang, Sheng Chang Wang, Shao Chieh Weng, Muhammad Omar Shaikh

Research output: Contribution to journalArticle

Abstract

Here, we demonstrate the enhanced water-splitting performance (I = 10 mA/cm2, Tafel slope = 60 mV/dec, onset potential = −80 mV) of atmospheric air plasma treated (AAPT) SnS thin films by the hydrogen evolution reaction (HER). The as prepared SnS films were subjected to Atmospheric Air Plasma Treatment (AAPT) which leads to formation of additional phases of Sn and SnO2 at plasma powers of 150 W and 250 W, respectively. The AAPT treatment at 150 W leads to the evaporation of the S atoms as SO2 generates a number of S-vacancies and Sn active edge sites over the surface of the SnS thin film. S-vacancies also create Sn active edge sites, surface p-type pinning that tunes the suitable band positions, and a hydrophilic surface which is beneficial for hydrogen adsorption/desorption. At high plasma power (250 W), the surface of the SnS films becomes oxidized and degrades the HER performance. These results demonstrate that AAPT (150 W) is capable of improving the HER performance of SnS thin films and our results indicate that SnS thin films can work as efficient electrocatalysts for HER.

Original languageEnglish
Article number462
JournalCatalysts
Volume8
Issue number10
DOIs
Publication statusPublished - 2018 Oct 17

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electrocatalysts
Electrocatalysts
Hydrogen
Plasmas
air
hydrogen
Air
Thin films
thin films
Vacancies
water splitting
Desorption
Evaporation
desorption
evaporation
slopes
Adsorption
Atoms
adsorption
Water

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

Huang, P. C., Brahma, S., Liu, P. Y., Huang, J-L., Wang, S. C., Weng, S. C., & Shaikh, M. O. (2018). Atmospheric air plasma treated SnS films: An efficient electrocatalyst for HER. Catalysts, 8(10), [462]. https://doi.org/10.3390/catal8100462
Huang, Po Chia ; Brahma, Sanjaya ; Liu, Po Yen ; Huang, Jow-Lay ; Wang, Sheng Chang ; Weng, Shao Chieh ; Shaikh, Muhammad Omar. / Atmospheric air plasma treated SnS films : An efficient electrocatalyst for HER. In: Catalysts. 2018 ; Vol. 8, No. 10.
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Huang, PC, Brahma, S, Liu, PY, Huang, J-L, Wang, SC, Weng, SC & Shaikh, MO 2018, 'Atmospheric air plasma treated SnS films: An efficient electrocatalyst for HER', Catalysts, vol. 8, no. 10, 462. https://doi.org/10.3390/catal8100462

Atmospheric air plasma treated SnS films : An efficient electrocatalyst for HER. / Huang, Po Chia; Brahma, Sanjaya; Liu, Po Yen; Huang, Jow-Lay; Wang, Sheng Chang; Weng, Shao Chieh; Shaikh, Muhammad Omar.

In: Catalysts, Vol. 8, No. 10, 462, 17.10.2018.

Research output: Contribution to journalArticle

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AU - Shaikh, Muhammad Omar

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