Bromide incorporation into a high-oxidation-state manganese aggregate, and reversible redox processes for the [Mn4O3X(OAc) 3(dbm)3] (X = Cl, Br) complexes

Sheyi Wang, Hui Lien Tsai, William E. Streib, George Christou, David N. Hendrickson

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

Treatment of [Mn4O2(OAc)6(py) 2(dbm)2] (dbmH = dibenzoylmethane) with either NBu n4Br in hot MeCN or Me3SiBr in CH 2Br2 leads to the 3MnIII, MnIV cubane complex [Mn4O3Br(OAc)3(dbm)3] 3, the initial example of Br- bridging high-oxidation-state (≥III) Mn ions; in addition, 3 and its Cl- analogue display similar and reversible redox processes and similar magnetic exchange interactions, observations of significant biological relevance to the photosynthetic water-oxidation enzyme.

Original languageEnglish
Pages (from-to)1427-1429
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number19
DOIs
Publication statusPublished - 1992 Dec 1

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Manganese
Bromides
Oxidation-Reduction
Ions
Oxidation
Water
Exchange interactions
Enzymes
dibenzoylmethane

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

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title = "Bromide incorporation into a high-oxidation-state manganese aggregate, and reversible redox processes for the [Mn4O3X(OAc) 3(dbm)3] (X = Cl, Br) complexes",
abstract = "Treatment of [Mn4O2(OAc)6(py) 2(dbm)2] (dbmH = dibenzoylmethane) with either NBu n4Br in hot MeCN or Me3SiBr in CH 2Br2 leads to the 3MnIII, MnIV cubane complex [Mn4O3Br(OAc)3(dbm)3] 3, the initial example of Br- bridging high-oxidation-state (≥III) Mn ions; in addition, 3 and its Cl- analogue display similar and reversible redox processes and similar magnetic exchange interactions, observations of significant biological relevance to the photosynthetic water-oxidation enzyme.",
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year = "1992",
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language = "English",
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Bromide incorporation into a high-oxidation-state manganese aggregate, and reversible redox processes for the [Mn4O3X(OAc) 3(dbm)3] (X = Cl, Br) complexes. / Wang, Sheyi; Tsai, Hui Lien; Streib, William E.; Christou, George; Hendrickson, David N.

In: Journal of the Chemical Society, Chemical Communications, No. 19, 01.12.1992, p. 1427-1429.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Bromide incorporation into a high-oxidation-state manganese aggregate, and reversible redox processes for the [Mn4O3X(OAc) 3(dbm)3] (X = Cl, Br) complexes

AU - Wang, Sheyi

AU - Tsai, Hui Lien

AU - Streib, William E.

AU - Christou, George

AU - Hendrickson, David N.

PY - 1992/12/1

Y1 - 1992/12/1

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AB - Treatment of [Mn4O2(OAc)6(py) 2(dbm)2] (dbmH = dibenzoylmethane) with either NBu n4Br in hot MeCN or Me3SiBr in CH 2Br2 leads to the 3MnIII, MnIV cubane complex [Mn4O3Br(OAc)3(dbm)3] 3, the initial example of Br- bridging high-oxidation-state (≥III) Mn ions; in addition, 3 and its Cl- analogue display similar and reversible redox processes and similar magnetic exchange interactions, observations of significant biological relevance to the photosynthetic water-oxidation enzyme.

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