Buckybowls on metal surfaces: Symmetry mismatch and enantiomorphism of corannulene on Cu(110)

Manfred Parschau; Roman Fasel; Karl Heinz Ernst; Oliver Gröning; Louis Brandenberger; Richard Schillinger; Thomas Greber; Ari P. Seitsonen; Yao Ting Wu; Jay S. Siegel

doi:10.1002/anie.200700610

Buckybowls on metal surfaces: Symmetry mismatch and enantiomorphism of corannulene on Cu(110)

Manfred Parschau
, Roman Fasel
, Karl Heinz Ernst
, Oliver Gröning
, Louis Brandenberger
, Richard Schillinger
, Thomas Greber
, Ari P. Seitsonen
, Yao Ting Wu
, Jay S. Siegel

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

85 Citations (Scopus)

Abstract

(Figure Presented) Fivefold versus twofold: Symmetry-breaking interactions in the monolayer of the buckybowl corannulene on Cu(110) lead to the formation of extended mirror domains (see picture). The molecules are adsorbed in a tilted geometry with the bowl opening pointing away from the surface.

Original language	English
Pages (from-to)	8258-8261
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	43
DOIs	https://doi.org/10.1002/anie.200700610
Publication status	Published - 2007

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

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10.1002/anie.200700610

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title = "Buckybowls on metal surfaces: Symmetry mismatch and enantiomorphism of corannulene on Cu(110)",

abstract = "(Figure Presented) Fivefold versus twofold: Symmetry-breaking interactions in the monolayer of the buckybowl corannulene on Cu(110) lead to the formation of extended mirror domains (see picture). The molecules are adsorbed in a tilted geometry with the bowl opening pointing away from the surface.",

author = "Manfred Parschau and Roman Fasel and Ernst, \{Karl Heinz\} and Oliver Gr{\"o}ning and Louis Brandenberger and Richard Schillinger and Thomas Greber and Seitsonen, \{Ari P.\} and Wu, \{Yao Ting\} and Siegel, \{Jay S.\}",

note = "Funding Information: This work was supported by the Chemical Systems Laboratory, U. S. Army, Aberdeen Proving Ground, and the Aerosol Research Branch, U.S. Environmental Protection Agency.",

year = "2007",

doi = "10.1002/anie.200700610",

language = "English",

volume = "46",

pages = "8258--8261",

journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Buckybowls on metal surfaces

T2 - Symmetry mismatch and enantiomorphism of corannulene on Cu(110)

AU - Parschau, Manfred

AU - Fasel, Roman

AU - Ernst, Karl Heinz

AU - Gröning, Oliver

AU - Brandenberger, Louis

AU - Schillinger, Richard

AU - Greber, Thomas

AU - Seitsonen, Ari P.

AU - Wu, Yao Ting

AU - Siegel, Jay S.

N1 - Funding Information: This work was supported by the Chemical Systems Laboratory, U. S. Army, Aberdeen Proving Ground, and the Aerosol Research Branch, U.S. Environmental Protection Agency.

PY - 2007

Y1 - 2007

N2 - (Figure Presented) Fivefold versus twofold: Symmetry-breaking interactions in the monolayer of the buckybowl corannulene on Cu(110) lead to the formation of extended mirror domains (see picture). The molecules are adsorbed in a tilted geometry with the bowl opening pointing away from the surface.

AB - (Figure Presented) Fivefold versus twofold: Symmetry-breaking interactions in the monolayer of the buckybowl corannulene on Cu(110) lead to the formation of extended mirror domains (see picture). The molecules are adsorbed in a tilted geometry with the bowl opening pointing away from the surface.

UR - https://www.scopus.com/pages/publications/36048941358

UR - https://www.scopus.com/pages/publications/36048941358#tab=citedBy

U2 - 10.1002/anie.200700610

DO - 10.1002/anie.200700610

M3 - Article

C2 - 17886816

AN - SCOPUS:36048941358

SN - 1433-7851

VL - 46

SP - 8258

EP - 8261

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 43

ER -

Buckybowls on metal surfaces: Symmetry mismatch and enantiomorphism of corannulene on Cu(110)

Abstract

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