Catalytic reduction of hydrazine to ammonia by a vanadium thiolate complex

Wei Cheng Chu, Chi Chin Wu, Hua-Fen Hsu

Research output: Contribution to journalArticlepeer-review

33 Citations (Scopus)

Abstract

Vanadium(III) thiolate complexes, [V(PS3″)(Cl)]- [1a; PS3″ = P(C6H3-3-Me3Si-2-S) 33-] and [V(PS3′)(Cl)]- [1b; PS3′ = P(C6H3-5-Me-2-S)33-], were synthesized and characterized. Complex 1a serves as a precursor for the catalytic reduction of hydrazine to ammonia. The spectroscopic and electrochemical studies indicate that hydrazine is bound and activated in a VII state.

Original languageEnglish
Pages (from-to)3164-3166
Number of pages3
JournalInorganic Chemistry
Volume45
Issue number8
DOIs
Publication statusPublished - 2006 Apr 17

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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