Catalytic reduction of hydrazine to ammonia by a vanadium thiolate complex

Wei Cheng Chu, Chi Chin Wu, Hua-Fen Hsu

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Vanadium(III) thiolate complexes, [V(PS3″)(Cl)]- [1a; PS3″ = P(C6H3-3-Me3Si-2-S) 33-] and [V(PS3′)(Cl)]- [1b; PS3′ = P(C6H3-5-Me-2-S)33-], were synthesized and characterized. Complex 1a serves as a precursor for the catalytic reduction of hydrazine to ammonia. The spectroscopic and electrochemical studies indicate that hydrazine is bound and activated in a VII state.

Original languageEnglish
Pages (from-to)3164-3166
Number of pages3
JournalInorganic Chemistry
Volume45
Issue number8
DOIs
Publication statusPublished - 2006 Apr 17

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hydrazine
Vanadium
hydrazines
Ammonia
vanadium
ammonia

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Chu, Wei Cheng ; Wu, Chi Chin ; Hsu, Hua-Fen. / Catalytic reduction of hydrazine to ammonia by a vanadium thiolate complex. In: Inorganic Chemistry. 2006 ; Vol. 45, No. 8. pp. 3164-3166.
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Catalytic reduction of hydrazine to ammonia by a vanadium thiolate complex. / Chu, Wei Cheng; Wu, Chi Chin; Hsu, Hua-Fen.

In: Inorganic Chemistry, Vol. 45, No. 8, 17.04.2006, p. 3164-3166.

Research output: Contribution to journalArticle

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