Characterization of the outer well of NaH C1Σ+ state by fluorescence depletion spectroscopy

Hsien Yu Huang; Yao Yuan Chang; Mei Hui Liao; Kuo Lung Wu; Tsai Lien Lu; Yung Yung Chang; Chin Chun Tsai; Thou Jen Whang

doi:10.1016/j.cplett.2010.05.035

Characterization of the outer well of NaH C¹Σ⁺ state by fluorescence depletion spectroscopy

Hsien Yu Huang, Yao Yuan Chang, Mei Hui Liao, Kuo Lung Wu, Tsai Lien Lu, Yung Yung Chang, Chin Chun Tsai, Thou Jen Whang

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The outer well of the NaH C¹Σ⁺ excited state was determined using pulsed optical-optical double resonance fluorescence depletion spectroscopy. The level-selected fluorescence of the A ¹Σ⁺ state is depleted back to the ground state when a probe laser excites the molecules to the C¹Σ⁺ state. A total of 456 rovibrational levels, v = 5-33 and J = 1-11, were observed. A set of Dunham constants and the Rydberg-Klein-Rees (RKR) potential curve for the outer well were reported.

Original language	English
Pages (from-to)	53-56
Number of pages	4
Journal	Chemical Physics Letters
Volume	493
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2010.05.035
Publication status	Published - 2010 Jun 17

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/j.cplett.2010.05.035

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title = "Characterization of the outer well of NaH C1Σ+ state by fluorescence depletion spectroscopy",

abstract = "The outer well of the NaH C1Σ+ excited state was determined using pulsed optical-optical double resonance fluorescence depletion spectroscopy. The level-selected fluorescence of the A 1Σ+ state is depleted back to the ground state when a probe laser excites the molecules to the C1Σ+ state. A total of 456 rovibrational levels, v = 5-33 and J = 1-11, were observed. A set of Dunham constants and the Rydberg-Klein-Rees (RKR) potential curve for the outer well were reported.",

author = "Huang, {Hsien Yu} and Chang, {Yao Yuan} and Liao, {Mei Hui} and Wu, {Kuo Lung} and Lu, {Tsai Lien} and Chang, {Yung Yung} and Tsai, {Chin Chun} and Whang, {Thou Jen}",

year = "2010",

month = jun,

day = "17",

doi = "10.1016/j.cplett.2010.05.035",

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T1 - Characterization of the outer well of NaH C1Σ+ state by fluorescence depletion spectroscopy

AU - Huang, Hsien Yu

AU - Chang, Yao Yuan

AU - Liao, Mei Hui

AU - Wu, Kuo Lung

AU - Lu, Tsai Lien

AU - Chang, Yung Yung

AU - Tsai, Chin Chun

AU - Whang, Thou Jen

PY - 2010/6/17

Y1 - 2010/6/17

N2 - The outer well of the NaH C1Σ+ excited state was determined using pulsed optical-optical double resonance fluorescence depletion spectroscopy. The level-selected fluorescence of the A 1Σ+ state is depleted back to the ground state when a probe laser excites the molecules to the C1Σ+ state. A total of 456 rovibrational levels, v = 5-33 and J = 1-11, were observed. A set of Dunham constants and the Rydberg-Klein-Rees (RKR) potential curve for the outer well were reported.

AB - The outer well of the NaH C1Σ+ excited state was determined using pulsed optical-optical double resonance fluorescence depletion spectroscopy. The level-selected fluorescence of the A 1Σ+ state is depleted back to the ground state when a probe laser excites the molecules to the C1Σ+ state. A total of 456 rovibrational levels, v = 5-33 and J = 1-11, were observed. A set of Dunham constants and the Rydberg-Klein-Rees (RKR) potential curve for the outer well were reported.

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DO - 10.1016/j.cplett.2010.05.035

M3 - Article

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SN - 0009-2614

VL - 493

SP - 53

EP - 56

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

Characterization of the outer well of NaH C¹Σ⁺ state by fluorescence depletion spectroscopy

Abstract

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