Characterization of ZnO:Ga transparent contact electrodes for microcrystalline silicon thin film solar cells

Kuang Chieh Lai, Chien Chih Liu, Chun hsiung Lu, Chih Hung Yeh, Mau Phon Houng

Research output: Contribution to journalReview article

30 Citations (Scopus)

Abstract

Gallium-doped zinc oxide (ZnO:Ga) thin films are of interest to the semiconductor industry as transparent conductive surfaces and as transparent contact electrode layers for applications such as microcrystalline silicon (μc-Si) thin film solar cells. Physical vapor deposition (PVD) via sputtering is commonly used to produce thin films such as ZnO:Ga, but film quality and characteristics depend significantly on the PVD processing parameters. For use as contact electrode layers in μc-Si thin film solar cells, this study investigates some of the important changes of ZnO:Ga thin films that result from varying DC magnetron PVD sputtering parameters, specifically the working power (500, 1200, and 1900 w), process gas (Ar, Ar/O2=50/0.2 sccm) and working pressure (0.74 and 1.06 Pa). Process temperature is held at 200 °C because thin film solar cells are damaged above 200 °C. Adding O2 to the Ar carrier gas improved transmittance but the resistivity suffered. However, high-sputtering power solved the resistivity problem. Additionally, the effects of the produced ZnO:Ga material when applied as multi-layer front and back layer electrodes to μc-Si thin film solar cells is evaluated in terms of open-circuit voltage (ΔVOC), short-circuit current density (ΔJSC), fill factor (ΔFF) and efficiency (Δη) of the cells.

Original languageEnglish
Pages (from-to)397-401
Number of pages5
JournalSolar Energy Materials and Solar Cells
Volume94
Issue number3
DOIs
Publication statusPublished - 2010 Mar 1

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All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films

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