Conductivity and characterization of plasticized polymer electrolyte based on (polyacrylonitrile-b-polyethylene glycol) copolymer

Yu Hao Liang, Cheng Chien Wang, Chuh Yung Chen

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

A block copolymer polyacrylonitrile-b-polyethylene glycol was synthesized by the macroinitiator method. The copolymer mixed with a plasticizer-propylene carbonate (PC) and LiClO4 to form plasticized polymer electrolytes. FT-IR spectra show that the lithium ion interacts with the groups that contain the un-bonded electrons. The results of FT-IR also indicate that the EO segment can improve the dissociation of lithium salt. The differential scanning calorimeter (DSC) used to study the thermal behaviors of different compositions. In this study, the conductivity increases with the content of PEG. Additionally, the plasticized polymer electrolyte based on the block copolymer has a good conductivity and can retain good mechanical strength.

Original languageEnglish
Pages (from-to)886-892
Number of pages7
JournalJournal of Power Sources
Volume172
Issue number2
DOIs
Publication statusPublished - 2007 Oct 25

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

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