Controllable-nitrogen doped carbon layer surrounding carbon nanotubes as novel carbon support for oxygen reduction reaction

P. L. Kuo, C. H. Hsu, H. M. Wu, W. S. Hsu, D. Kuo

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Novel nitrogen-doped carbon layer surrounding carbon nanotubes composite (NC-CNT) (N/C ratio 3.3-14.3wt.%) as catalyst support has been prepared using aniline as a dispersant to carbon nanotubes (CNTs) and as a source for both carbon and nitrogen coated on the surface of the CNTs, where the amount of doped nitrogen is controllable. The NC-CNT so obtained were characterized with scanning electron microscopy (SEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption and desorption isotherms. A uniform dispersion of Pt nanoparticles (ca. 1.5-2.0nm) was then anchored on the surface of NC-CNT by using aromatic amine as a stabilizer. For these Pt/NC-CNTs, cyclic voltammogram measurements show a high electrochemical activity surface area (up to 103.7m 2g -1) compared to the commercial E-TEK catalyst (55.3m 2g -1). In single cell test, Pt/NC-CNT catalyst has greatly enhanced catalytic activity toward the oxygen reduction reaction, resulting in an enhancement of ca. 37% in mass activity compared with that of E-TEK.

Original languageEnglish
Pages (from-to)649-655
Number of pages7
JournalFuel Cells
Volume12
Issue number4
DOIs
Publication statusPublished - 2012 Aug 1

Fingerprint

Carbon nanotubes
Nitrogen
Carbon
Oxygen
Catalysts
Aniline
Catalyst supports
Isotherms
Raman spectroscopy
Amines
Catalyst activity
Desorption
X ray photoelectron spectroscopy
Nanoparticles
Adsorption
Scanning electron microscopy
Composite materials

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology

Cite this

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title = "Controllable-nitrogen doped carbon layer surrounding carbon nanotubes as novel carbon support for oxygen reduction reaction",
abstract = "Novel nitrogen-doped carbon layer surrounding carbon nanotubes composite (NC-CNT) (N/C ratio 3.3-14.3wt.{\%}) as catalyst support has been prepared using aniline as a dispersant to carbon nanotubes (CNTs) and as a source for both carbon and nitrogen coated on the surface of the CNTs, where the amount of doped nitrogen is controllable. The NC-CNT so obtained were characterized with scanning electron microscopy (SEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption and desorption isotherms. A uniform dispersion of Pt nanoparticles (ca. 1.5-2.0nm) was then anchored on the surface of NC-CNT by using aromatic amine as a stabilizer. For these Pt/NC-CNTs, cyclic voltammogram measurements show a high electrochemical activity surface area (up to 103.7m 2g -1) compared to the commercial E-TEK catalyst (55.3m 2g -1). In single cell test, Pt/NC-CNT catalyst has greatly enhanced catalytic activity toward the oxygen reduction reaction, resulting in an enhancement of ca. 37{\%} in mass activity compared with that of E-TEK.",
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Controllable-nitrogen doped carbon layer surrounding carbon nanotubes as novel carbon support for oxygen reduction reaction. / Kuo, P. L.; Hsu, C. H.; Wu, H. M.; Hsu, W. S.; Kuo, D.

In: Fuel Cells, Vol. 12, No. 4, 01.08.2012, p. 649-655.

Research output: Contribution to journalArticle

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