Controlling morphology and crystallite size of Cu(In0.7Ga 0.3)Se2 nano-crystals synthesized using a heating-up method

Wei Hsiang Hsu, Hsing-I Hsiang, Chih Ta Chia, Fu Su Yen

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

CuIn0.7Ga0.3Se2(CIGS) nano-crystals were successfully synthesized via a heating-up process. The non-coordinating solvent (1-octadecene) and selenium/cations ratio effects on the crystalline phase and crystallite size of CIGS nano-crystallites were investigated. It was observed that the CIGS nano-crystallite morphology changed from sheet into spherical shape as the amount of 1-octadecene addition was increased. CIGS nano-crystals were obtained in 9-20 nm sizes as the selenium/cations ratio increased. These results suggest that the monomer reactivity in the solution can be adjusted by changing the solvent type and selenium/cations ratio, hence affecting the crystallite size and distribution.

Original languageEnglish
Pages (from-to)1-8
Number of pages8
JournalJournal of Solid State Chemistry
Volume208
DOIs
Publication statusPublished - 2013 Oct 11

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Selenium
Crystallite size
selenium
Cations
Positive ions
Heating
cations
Crystals
heating
crystals
Crystallites
crystallites
reactivity
monomers
Monomers
Crystalline materials
1-octadecene

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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title = "Controlling morphology and crystallite size of Cu(In0.7Ga 0.3)Se2 nano-crystals synthesized using a heating-up method",
abstract = "CuIn0.7Ga0.3Se2(CIGS) nano-crystals were successfully synthesized via a heating-up process. The non-coordinating solvent (1-octadecene) and selenium/cations ratio effects on the crystalline phase and crystallite size of CIGS nano-crystallites were investigated. It was observed that the CIGS nano-crystallite morphology changed from sheet into spherical shape as the amount of 1-octadecene addition was increased. CIGS nano-crystals were obtained in 9-20 nm sizes as the selenium/cations ratio increased. These results suggest that the monomer reactivity in the solution can be adjusted by changing the solvent type and selenium/cations ratio, hence affecting the crystallite size and distribution.",
author = "Hsu, {Wei Hsiang} and Hsing-I Hsiang and Chia, {Chih Ta} and Yen, {Fu Su}",
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Controlling morphology and crystallite size of Cu(In0.7Ga 0.3)Se2 nano-crystals synthesized using a heating-up method. / Hsu, Wei Hsiang; Hsiang, Hsing-I; Chia, Chih Ta; Yen, Fu Su.

In: Journal of Solid State Chemistry, Vol. 208, 11.10.2013, p. 1-8.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Controlling morphology and crystallite size of Cu(In0.7Ga 0.3)Se2 nano-crystals synthesized using a heating-up method

AU - Hsu, Wei Hsiang

AU - Hsiang, Hsing-I

AU - Chia, Chih Ta

AU - Yen, Fu Su

PY - 2013/10/11

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N2 - CuIn0.7Ga0.3Se2(CIGS) nano-crystals were successfully synthesized via a heating-up process. The non-coordinating solvent (1-octadecene) and selenium/cations ratio effects on the crystalline phase and crystallite size of CIGS nano-crystallites were investigated. It was observed that the CIGS nano-crystallite morphology changed from sheet into spherical shape as the amount of 1-octadecene addition was increased. CIGS nano-crystals were obtained in 9-20 nm sizes as the selenium/cations ratio increased. These results suggest that the monomer reactivity in the solution can be adjusted by changing the solvent type and selenium/cations ratio, hence affecting the crystallite size and distribution.

AB - CuIn0.7Ga0.3Se2(CIGS) nano-crystals were successfully synthesized via a heating-up process. The non-coordinating solvent (1-octadecene) and selenium/cations ratio effects on the crystalline phase and crystallite size of CIGS nano-crystallites were investigated. It was observed that the CIGS nano-crystallite morphology changed from sheet into spherical shape as the amount of 1-octadecene addition was increased. CIGS nano-crystals were obtained in 9-20 nm sizes as the selenium/cations ratio increased. These results suggest that the monomer reactivity in the solution can be adjusted by changing the solvent type and selenium/cations ratio, hence affecting the crystallite size and distribution.

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