Covalent linkage of [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 ] into a dimer and a one-dimensional polymer (dbmH = dibenzoylmethane)

Sheyi Wang, Hui-Lien Tsai, Kirsten Folting, James D. Martin, David N. Hendrickson, George Christou

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

Methods have been developed for covalently linking [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 ] 2 (dbmH = dibenzoylmethane) units to give a dimer and a polymer; treatment of 2 with trans-1,2-bis(4-pyridyl)ethene (bpe) or 4,4′-bipyridine (4,4′-bpy) yields [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 (bpe)] 2 4 and [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 (4,4′-bpy)] n 5, respectively.

Original languageEnglish
Pages (from-to)671-673
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number5
DOIs
Publication statusPublished - 1994 Dec 1

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Dimers
Polymers
1,2-bis(4-pyridyl)ethene
dibenzoylmethane

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

@article{97e390645f2f407d88284e4ed7916288,
title = "Covalent linkage of [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 ] into a dimer and a one-dimensional polymer (dbmH = dibenzoylmethane)",
abstract = "Methods have been developed for covalently linking [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 ] 2 (dbmH = dibenzoylmethane) units to give a dimer and a polymer; treatment of 2 with trans-1,2-bis(4-pyridyl)ethene (bpe) or 4,4′-bipyridine (4,4′-bpy) yields [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 (bpe)] 2 4 and [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 (4,4′-bpy)] n 5, respectively.",
author = "Sheyi Wang and Hui-Lien Tsai and Kirsten Folting and Martin, {James D.} and Hendrickson, {David N.} and George Christou",
year = "1994",
month = "12",
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doi = "10.1039/C39940000671",
language = "English",
pages = "671--673",
journal = "Chemical Communications",
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publisher = "Royal Society of Chemistry",
number = "5",

}

Covalent linkage of [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 ] into a dimer and a one-dimensional polymer (dbmH = dibenzoylmethane) . / Wang, Sheyi; Tsai, Hui-Lien; Folting, Kirsten; Martin, James D.; Hendrickson, David N.; Christou, George.

In: Journal of the Chemical Society, Chemical Communications, No. 5, 01.12.1994, p. 671-673.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Covalent linkage of [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 ] into a dimer and a one-dimensional polymer (dbmH = dibenzoylmethane)

AU - Wang, Sheyi

AU - Tsai, Hui-Lien

AU - Folting, Kirsten

AU - Martin, James D.

AU - Hendrickson, David N.

AU - Christou, George

PY - 1994/12/1

Y1 - 1994/12/1

N2 - Methods have been developed for covalently linking [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 ] 2 (dbmH = dibenzoylmethane) units to give a dimer and a polymer; treatment of 2 with trans-1,2-bis(4-pyridyl)ethene (bpe) or 4,4′-bipyridine (4,4′-bpy) yields [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 (bpe)] 2 4 and [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 (4,4′-bpy)] n 5, respectively.

AB - Methods have been developed for covalently linking [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 ] 2 (dbmH = dibenzoylmethane) units to give a dimer and a polymer; treatment of 2 with trans-1,2-bis(4-pyridyl)ethene (bpe) or 4,4′-bipyridine (4,4′-bpy) yields [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 (bpe)] 2 4 and [Mn 4 O 2 (O 2 CPh) 6 (dbm) 2 (4,4′-bpy)] n 5, respectively.

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