Crystal engineering: Toward intersecting channels from a neutral network with a bcu-type topology

Tzuoo Tsair Luo; Hui Lien Tsai; Shang Li Yang; Yen Hsiang Liu; R. Dayal Yadav; Chan Cheng Su; Chuen Her Ueng; Lee Gin Lin; Kuang Lieh Lu

doi:10.1002/anie.200462674

Crystal engineering: Toward intersecting channels from a neutral network with a bcu-type topology

Tzuoo Tsair Luo, Hui Lien Tsai, Shang Li Yang, Yen Hsiang Liu, R. Dayal Yadav, Chan Cheng Su, Chuen Her Ueng, Lee Gin Lin, Kuang Lieh Lu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

206 Citations (Scopus)

Abstract

(Chemical Equation Presented) In rare form: Although the structure of the body-centered cubic (bcu) net is commonly found in textbooks, its eight-connected topology is extremely rare in metal-organic frameworks owing to severe geometric requirements. The first example of a highly porous, neutral bcu-type framework (see picture) assembled from a unique eight-connected tricopper cluster and a 5-(4-pyridyl)tetrazolate ligand as linker is reported.

Original language	English
Pages (from-to)	6063-6067
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	37
DOIs	https://doi.org/10.1002/anie.200462674
Publication status	Published - 2005 Sept 19

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

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10.1002/anie.200462674

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abstract = "(Chemical Equation Presented) In rare form: Although the structure of the body-centered cubic (bcu) net is commonly found in textbooks, its eight-connected topology is extremely rare in metal-organic frameworks owing to severe geometric requirements. The first example of a highly porous, neutral bcu-type framework (see picture) assembled from a unique eight-connected tricopper cluster and a 5-(4-pyridyl)tetrazolate ligand as linker is reported.",

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AU - Liu, Yen Hsiang

AU - Yadav, R. Dayal

AU - Su, Chan Cheng

AU - Ueng, Chuen Her

AU - Lin, Lee Gin

AU - Lu, Kuang Lieh

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Crystal engineering: Toward intersecting channels from a neutral network with a bcu-type topology

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