Crystal engineering: Toward intersecting channels from a neutral network with a bcu-type topology

Tzuoo Tsair Luo, Hui Lien Tsai, Shang Li Yang, Yen Hsiang Liu, R. Dayal Yadav, Chan Cheng Su, Chuen Her Ueng, Lee Gin Lin, Kuang Lieh Lu

Research output: Contribution to journalArticlepeer-review

203 Citations (Scopus)

Abstract

(Chemical Equation Presented) In rare form: Although the structure of the body-centered cubic (bcu) net is commonly found in textbooks, its eight-connected topology is extremely rare in metal-organic frameworks owing to severe geometric requirements. The first example of a highly porous, neutral bcu-type framework (see picture) assembled from a unique eight-connected tricopper cluster and a 5-(4-pyridyl)tetrazolate ligand as linker is reported.

Original languageEnglish
Pages (from-to)6063-6067
Number of pages5
JournalAngewandte Chemie - International Edition
Volume44
Issue number37
DOIs
Publication statusPublished - 2005 Sep 19

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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