Crystallization of lanthanum-modified lead zirconate titanate (Plzt) using coprecipitated gels

Yao Jung Lee, Fu Su Yen, Jong Ping Wu, Hsing I. Hsiang

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2 Citations (Scopus)

Abstract

Powders of lanthanum-modified lead zirconate titanate (Pb0.91La0.09)(Zr0.65Ti0.35)0.98O3 (PLZT 9/65/35) were obtained by calcination of various precursors via chemical coprecipitation methods. The precursors included the coprecipitated gel with the stoichiometric PLZT composition, PbO (powdered chemical reagent)+LZT coprecipitated gel, and mixture of Pb, La, Zr, and Ti individually precipitated gels. Crystallization behaviors of these precursors were examined over the temperature range of 400°-900°C using X-ray diffraction (XRD), transmission electron microscopy (TEM) and differential thermal analysis/thermal gravimetric analysis (DTA/TGA) techniques. For coprecipitated PLZT gels, perovskite PLZT accompanied by pyrochlore crystallized at 500°C; further heating promoted the development of PLZT, and single-phase PLZT was achieved at 700°C. For PbO + LZT coprecipitated gels, PLZT began to form at 550°C. The formation reaction was complete at 800°C and only a limited amount of pyrochlore intermediate was detected by XRD. For the mixture of Pb, La, Zr, and Ti gels, PLZT crystallized at 900°C, litharge, massicot, PbTiO3(PT), and PbZrO3(PZ) were formed as the intermediate phase instead of pyrochlore.

Original languageEnglish
Pages (from-to)4137-4142
Number of pages6
JournalJapanese Journal of Applied Physics
Volume34
Issue number8 R
DOIs
Publication statusPublished - 1995 Aug

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physics and Astronomy(all)

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