Abstract
The oil tanks of gas station and petrochemical industry are installed underg round, and the BTEX in the oil might affect the soil and underground water seriously and pose a threat to the neighbourhoods. Fenton-like oxidation is derived from in situ chemical oxidation remediation of soil and underground water. Catalysis of H2O2 by iron based materials produces free radicals which could destroy the organic pollutants in soils and underground water therefore reduces their toxicity level and mineralize them to H2 O and CO2. By having advantag es such as low cos t, accessible and non-toxic, Fenton-like oxidation have great potential in development. This study synthesizes iron based materials and apply to Fenton-like oxidation, then utilized Fenton-like reaction to treat benzene and MTBE pollutants. The results show the optimal operation condition of IBM (Iron-based material, IBM) is 250 g/L, H2O2 concentration is 23.52 mM. With natural pH and 4 hours reaction time, the removal efficiency of IBM (A) and IBM (B) to Benzene is 65% and 55%, respectively. And the removal efficiency to MTBE is 47% and 33%. By Fenton-like reaction, IBM (A) and IBM (B) has the potential to be used as the material for permeable reactive barrier to treat Benzene and MTBE pollutants.
| Original language | English |
|---|---|
| Title of host publication | EARTH 2015 - Proceedings of the 13th International Symposium on East Asian Resources Recycling Technology |
| Publisher | International Symposium on East Asian Resources Recycling Technology |
| Pages | 1070-1078 |
| Number of pages | 9 |
| Publication status | Published - 2015 |
| Event | 13th International Symposium on East Asian Resources Recycling Technology, EARTH 2015 - Pattaya, Thailand Duration: 2015 Nov 1 → 2015 Nov 4 |
Other
| Other | 13th International Symposium on East Asian Resources Recycling Technology, EARTH 2015 |
|---|---|
| Country | Thailand |
| City | Pattaya |
| Period | 15-11-01 → 15-11-04 |
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All Science Journal Classification (ASJC) codes
- Environmental Science(all)
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Degradation of persistent organic pollutants by fenton-like reactions in sustained release form. / Lu, Hsing Cheng; Hou, Wen-Che; Chang, Juu-En; Chen, Hung Ta; Wu, Chang Han.
EARTH 2015 - Proceedings of the 13th International Symposium on East Asian Resources Recycling Technology. International Symposium on East Asian Resources Recycling Technology, 2015. p. 1070-1078.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
TY - GEN
T1 - Degradation of persistent organic pollutants by fenton-like reactions in sustained release form
AU - Lu, Hsing Cheng
AU - Hou, Wen-Che
AU - Chang, Juu-En
AU - Chen, Hung Ta
AU - Wu, Chang Han
PY - 2015
Y1 - 2015
N2 - The oil tanks of gas station and petrochemical industry are installed underg round, and the BTEX in the oil might affect the soil and underground water seriously and pose a threat to the neighbourhoods. Fenton-like oxidation is derived from in situ chemical oxidation remediation of soil and underground water. Catalysis of H2O2 by iron based materials produces free radicals which could destroy the organic pollutants in soils and underground water therefore reduces their toxicity level and mineralize them to H2 O and CO2. By having advantag es such as low cos t, accessible and non-toxic, Fenton-like oxidation have great potential in development. This study synthesizes iron based materials and apply to Fenton-like oxidation, then utilized Fenton-like reaction to treat benzene and MTBE pollutants. The results show the optimal operation condition of IBM (Iron-based material, IBM) is 250 g/L, H2O2 concentration is 23.52 mM. With natural pH and 4 hours reaction time, the removal efficiency of IBM (A) and IBM (B) to Benzene is 65% and 55%, respectively. And the removal efficiency to MTBE is 47% and 33%. By Fenton-like reaction, IBM (A) and IBM (B) has the potential to be used as the material for permeable reactive barrier to treat Benzene and MTBE pollutants.
AB - The oil tanks of gas station and petrochemical industry are installed underg round, and the BTEX in the oil might affect the soil and underground water seriously and pose a threat to the neighbourhoods. Fenton-like oxidation is derived from in situ chemical oxidation remediation of soil and underground water. Catalysis of H2O2 by iron based materials produces free radicals which could destroy the organic pollutants in soils and underground water therefore reduces their toxicity level and mineralize them to H2 O and CO2. By having advantag es such as low cos t, accessible and non-toxic, Fenton-like oxidation have great potential in development. This study synthesizes iron based materials and apply to Fenton-like oxidation, then utilized Fenton-like reaction to treat benzene and MTBE pollutants. The results show the optimal operation condition of IBM (Iron-based material, IBM) is 250 g/L, H2O2 concentration is 23.52 mM. With natural pH and 4 hours reaction time, the removal efficiency of IBM (A) and IBM (B) to Benzene is 65% and 55%, respectively. And the removal efficiency to MTBE is 47% and 33%. By Fenton-like reaction, IBM (A) and IBM (B) has the potential to be used as the material for permeable reactive barrier to treat Benzene and MTBE pollutants.
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M3 - Conference contribution
SP - 1070
EP - 1078
BT - EARTH 2015 - Proceedings of the 13th International Symposium on East Asian Resources Recycling Technology
PB - International Symposium on East Asian Resources Recycling Technology
ER -