Determination of the absolute rate constants for free-radical polymerization

Kuo Jen-Feng, Chuh-Yung Chen

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The absolute rate constants for the propagation and termination of free-radical polymerization were determined by the convenient kinetic data without need for photo-illumination technique. The extent of recombination reaction occurring in the termination reactions can be obtained using the same experimental data. The homopolymerizations of styrene and methyl methacrylate are illustrated. The results obtained by this method are close to those in the literature.

Original languageEnglish
Pages (from-to)453-457
Number of pages5
JournalPolymer Journal
Volume13
Issue number5
DOIs
Publication statusPublished - 1981 Jan 1

Fingerprint

Styrene
Methacrylates
Free radical polymerization
Homopolymerization
Rate constants
Lighting
Kinetics

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Materials Chemistry

Cite this

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abstract = "The absolute rate constants for the propagation and termination of free-radical polymerization were determined by the convenient kinetic data without need for photo-illumination technique. The extent of recombination reaction occurring in the termination reactions can be obtained using the same experimental data. The homopolymerizations of styrene and methyl methacrylate are illustrated. The results obtained by this method are close to those in the literature.",
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Determination of the absolute rate constants for free-radical polymerization. / Jen-Feng, Kuo; Chen, Chuh-Yung.

In: Polymer Journal, Vol. 13, No. 5, 01.01.1981, p. 453-457.

Research output: Contribution to journalArticle

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AB - The absolute rate constants for the propagation and termination of free-radical polymerization were determined by the convenient kinetic data without need for photo-illumination technique. The extent of recombination reaction occurring in the termination reactions can be obtained using the same experimental data. The homopolymerizations of styrene and methyl methacrylate are illustrated. The results obtained by this method are close to those in the literature.

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