Dinuclear copper(II) complexes incorporating a new pyrazolo-based sulfur-containing binucleating ligand

Jeh Li Chou, Den Nan Horng, Jong Pyng Chyn, Kwang Ming Lee, F. L. Urbach, Gene Hsiang Lee, Hui Lien Tsai

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The new binucleating ligand 3,5-bis(1′-(4′-(2″-pyridyl)-2′-thiabutyl))pyrazole (BLEP) and two dicopper complexes [Cu2(BLEP)(μ-N3)(N3)2] (1) and [Cu2(BLEP)(μ-Br)(Br)(H2O)]Br (2) were synthesized. The X-ray structure investigation of this system revealed that the two copper centers are bridged by the central pyrazolyl group of BLEP and one azide (in 1) or bromide (in 2), and the side arm of the ligand coordinates to each of the coppers with one pyridyl N and one thia S.

Original languageEnglish
Pages (from-to)392-395
Number of pages4
JournalInorganic Chemistry Communications
Volume2
Issue number9
DOIs
Publication statusPublished - 1999 Sep 1

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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