Dinuclear copper(II) complexes incorporating a new pyrazolo-based sulfur-containing binucleating ligand

Jeh Li Chou; Den Nan Horng; Jong Pyng Chyn; Kwang Ming Lee; F. L. Urbach; Gene Hsiang Lee; Hui Lien Tsai

doi:10.1016/S1387-7003(99)00102-1

Dinuclear copper(II) complexes incorporating a new pyrazolo-based sulfur-containing binucleating ligand

Jeh Li Chou, Den Nan Horng, Jong Pyng Chyn, Kwang Ming Lee, F. L. Urbach, Gene Hsiang Lee, Hui Lien Tsai

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The new binucleating ligand 3,5-bis(1′-(4′-(2″-pyridyl)-2′-thiabutyl))pyrazole (BLEP) and two dicopper complexes [Cu₂(BLEP)(μ-N₃)(N₃)₂] (1) and [Cu₂(BLEP)(μ-Br)(Br)(H₂O)]Br (2) were synthesized. The X-ray structure investigation of this system revealed that the two copper centers are bridged by the central pyrazolyl group of BLEP and one azide (in 1) or bromide (in 2), and the side arm of the ligand coordinates to each of the coppers with one pyridyl N and one thia S.

Original language	English
Pages (from-to)	392-395
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	2
Issue number	9
DOIs	https://doi.org/10.1016/S1387-7003(99)00102-1
Publication status	Published - 1999 Sept 1

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S1387-7003(99)00102-1

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@article{10c0020ee12c4f1cb8416d0c8d4bd8e2,

title = "Dinuclear copper(II) complexes incorporating a new pyrazolo-based sulfur-containing binucleating ligand",

abstract = "The new binucleating ligand 3,5-bis(1′-(4′-(2″-pyridyl)-2′-thiabutyl))pyrazole (BLEP) and two dicopper complexes [Cu2(BLEP)(μ-N3)(N3)2] (1) and [Cu2(BLEP)(μ-Br)(Br)(H2O)]Br (2) were synthesized. The X-ray structure investigation of this system revealed that the two copper centers are bridged by the central pyrazolyl group of BLEP and one azide (in 1) or bromide (in 2), and the side arm of the ligand coordinates to each of the coppers with one pyridyl N and one thia S.",

author = "Chou, {Jeh Li} and Horng, {Den Nan} and Chyn, {Jong Pyng} and Lee, {Kwang Ming} and Urbach, {F. L.} and Lee, {Gene Hsiang} and Tsai, {Hui Lien}",

note = "Funding Information: Research grants from the National Science Council of Taiwan and The Chinese Military Academy are much appreciated.",

year = "1999",

month = sep,

day = "1",

doi = "10.1016/S1387-7003(99)00102-1",

language = "English",

volume = "2",

pages = "392--395",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier BV",

number = "9",

}

TY - JOUR

T1 - Dinuclear copper(II) complexes incorporating a new pyrazolo-based sulfur-containing binucleating ligand

AU - Chou, Jeh Li

AU - Horng, Den Nan

AU - Chyn, Jong Pyng

AU - Lee, Kwang Ming

AU - Urbach, F. L.

AU - Lee, Gene Hsiang

AU - Tsai, Hui Lien

N1 - Funding Information: Research grants from the National Science Council of Taiwan and The Chinese Military Academy are much appreciated.

PY - 1999/9/1

Y1 - 1999/9/1

N2 - The new binucleating ligand 3,5-bis(1′-(4′-(2″-pyridyl)-2′-thiabutyl))pyrazole (BLEP) and two dicopper complexes [Cu2(BLEP)(μ-N3)(N3)2] (1) and [Cu2(BLEP)(μ-Br)(Br)(H2O)]Br (2) were synthesized. The X-ray structure investigation of this system revealed that the two copper centers are bridged by the central pyrazolyl group of BLEP and one azide (in 1) or bromide (in 2), and the side arm of the ligand coordinates to each of the coppers with one pyridyl N and one thia S.

AB - The new binucleating ligand 3,5-bis(1′-(4′-(2″-pyridyl)-2′-thiabutyl))pyrazole (BLEP) and two dicopper complexes [Cu2(BLEP)(μ-N3)(N3)2] (1) and [Cu2(BLEP)(μ-Br)(Br)(H2O)]Br (2) were synthesized. The X-ray structure investigation of this system revealed that the two copper centers are bridged by the central pyrazolyl group of BLEP and one azide (in 1) or bromide (in 2), and the side arm of the ligand coordinates to each of the coppers with one pyridyl N and one thia S.

UR - http://www.scopus.com/inward/record.url?scp=0033420312&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033420312&partnerID=8YFLogxK

U2 - 10.1016/S1387-7003(99)00102-1

DO - 10.1016/S1387-7003(99)00102-1

M3 - Article

AN - SCOPUS:0033420312

SN - 1387-7003

VL - 2

SP - 392

EP - 395

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 9

ER -

Dinuclear copper(II) complexes incorporating a new pyrazolo-based sulfur-containing binucleating ligand

Abstract

All Science Journal Classification (ASJC) codes

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