Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers

Yi Fang Tsai, Gui Shih Huang, Chen I. Yang, Hui-Lien Tsai, Yi Hung Liu, Ting Shen Kuo, Hua-Fen Hsu

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Two dinuclear oxovanadium(IV) thiolate complexes, [N(C5H 11)4]2-[VOL1]2 (1) and [N(C 4H9)4][(VOL2)2(μ-OCH 3)] (2) (where L1 = [(CH3)SiO(C6H 4-2-S)2]3- and L2 = [(C6H 5)PO(C6H4-2-S)2]2-), have been synthesized and characterized. The geometry of the anion in 1 can be classified to an edge-sharing bi-square-pyramid with a syn-orthogonal configuration. The one in 2 can be view as a face-sharing bioctahedron with two oxo groups in syn positions. Of note, these two complexes display intramolecular ferromagnetic interaction between two metal centers.

Original languageEnglish
Pages (from-to)10467-10469
Number of pages3
JournalInorganic Chemistry
Volume46
Issue number25
DOIs
Publication statusPublished - 2007 Dec 10

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Vanadium
pyramids
vanadium
Anions
Metals
anions
Geometry
geometry
configurations
metals
interactions
oxovanadium IV

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Tsai, Yi Fang ; Huang, Gui Shih ; Yang, Chen I. ; Tsai, Hui-Lien ; Liu, Yi Hung ; Kuo, Ting Shen ; Hsu, Hua-Fen. / Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers. In: Inorganic Chemistry. 2007 ; Vol. 46, No. 25. pp. 10467-10469.
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abstract = "Two dinuclear oxovanadium(IV) thiolate complexes, [N(C5H 11)4]2-[VOL1]2 (1) and [N(C 4H9)4][(VOL2)2(μ-OCH 3)] (2) (where L1 = [(CH3)SiO(C6H 4-2-S)2]3- and L2 = [(C6H 5)PO(C6H4-2-S)2]2-), have been synthesized and characterized. The geometry of the anion in 1 can be classified to an edge-sharing bi-square-pyramid with a syn-orthogonal configuration. The one in 2 can be view as a face-sharing bioctahedron with two oxo groups in syn positions. Of note, these two complexes display intramolecular ferromagnetic interaction between two metal centers.",
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Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers. / Tsai, Yi Fang; Huang, Gui Shih; Yang, Chen I.; Tsai, Hui-Lien; Liu, Yi Hung; Kuo, Ting Shen; Hsu, Hua-Fen.

In: Inorganic Chemistry, Vol. 46, No. 25, 10.12.2007, p. 10467-10469.

Research output: Contribution to journalArticle

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AU - Tsai, Yi Fang

AU - Huang, Gui Shih

AU - Yang, Chen I.

AU - Tsai, Hui-Lien

AU - Liu, Yi Hung

AU - Kuo, Ting Shen

AU - Hsu, Hua-Fen

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