Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers

Yi Fang Tsai, Gui Shih Huang, Chen I. Yang, Hui Lien Tsai, Yi Hung Liu, Ting Shen Kuo, Hua Fen Hsu

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Two dinuclear oxovanadium(IV) thiolate complexes, [N(C5H 11)4]2-[VOL1]2 (1) and [N(C 4H9)4][(VOL2)2(μ-OCH 3)] (2) (where L1 = [(CH3)SiO(C6H 4-2-S)2]3- and L2 = [(C6H 5)PO(C6H4-2-S)2]2-), have been synthesized and characterized. The geometry of the anion in 1 can be classified to an edge-sharing bi-square-pyramid with a syn-orthogonal configuration. The one in 2 can be view as a face-sharing bioctahedron with two oxo groups in syn positions. Of note, these two complexes display intramolecular ferromagnetic interaction between two metal centers.

Original languageEnglish
Pages (from-to)10467-10469
Number of pages3
JournalInorganic Chemistry
Volume46
Issue number25
DOIs
Publication statusPublished - 2007 Dec 10

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Vanadium
pyramids
vanadium
Anions
Metals
anions
Geometry
geometry
configurations
metals
interactions
oxovanadium IV

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Tsai, Yi Fang ; Huang, Gui Shih ; Yang, Chen I. ; Tsai, Hui Lien ; Liu, Yi Hung ; Kuo, Ting Shen ; Hsu, Hua Fen. / Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers. In: Inorganic Chemistry. 2007 ; Vol. 46, No. 25. pp. 10467-10469.
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abstract = "Two dinuclear oxovanadium(IV) thiolate complexes, [N(C5H 11)4]2-[VOL1]2 (1) and [N(C 4H9)4][(VOL2)2(μ-OCH 3)] (2) (where L1 = [(CH3)SiO(C6H 4-2-S)2]3- and L2 = [(C6H 5)PO(C6H4-2-S)2]2-), have been synthesized and characterized. The geometry of the anion in 1 can be classified to an edge-sharing bi-square-pyramid with a syn-orthogonal configuration. The one in 2 can be view as a face-sharing bioctahedron with two oxo groups in syn positions. Of note, these two complexes display intramolecular ferromagnetic interaction between two metal centers.",
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Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers. / Tsai, Yi Fang; Huang, Gui Shih; Yang, Chen I.; Tsai, Hui Lien; Liu, Yi Hung; Kuo, Ting Shen; Hsu, Hua Fen.

In: Inorganic Chemistry, Vol. 46, No. 25, 10.12.2007, p. 10467-10469.

Research output: Contribution to journalArticle

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AU - Tsai, Yi Fang

AU - Huang, Gui Shih

AU - Yang, Chen I.

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AU - Liu, Yi Hung

AU - Kuo, Ting Shen

AU - Hsu, Hua Fen

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