Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers

Yi Fang Tsai; Gui Shih Huang; Chen I. Yang; Hui Lien Tsai; Yi Hung Liu; Ting Shen Kuo; Hua Fen Hsu

doi:10.1021/ic7017117

Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers

Yi Fang Tsai, Gui Shih Huang, Chen I. Yang, Hui Lien Tsai, Yi Hung Liu, Ting Shen Kuo, Hua Fen Hsu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Two dinuclear oxovanadium(IV) thiolate complexes, [N(C₅H ₁₁)₄]₂-[VOL1]₂ (1) and [N(C ₄H₉)₄][(VOL2)₂(μ-OCH ₃)] (2) (where L1 = [(CH₃)SiO(C₆H ₄-2-S)₂]^3- and L2 = [(C₆H ₅)PO(C₆H₄-2-S)₂]^2-), have been synthesized and characterized. The geometry of the anion in 1 can be classified to an edge-sharing bi-square-pyramid with a syn-orthogonal configuration. The one in 2 can be view as a face-sharing bioctahedron with two oxo groups in syn positions. Of note, these two complexes display intramolecular ferromagnetic interaction between two metal centers.

Original language	English
Pages (from-to)	10467-10469
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	25
DOIs	https://doi.org/10.1021/ic7017117
Publication status	Published - 2007 Dec 10

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic7017117

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@article{8b8560793b844079a484197e8e4361c1,

title = "Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers",

abstract = "Two dinuclear oxovanadium(IV) thiolate complexes, [N(C5H 11)4]2-[VOL1]2 (1) and [N(C 4H9)4][(VOL2)2(μ-OCH 3)] (2) (where L1 = [(CH3)SiO(C6H 4-2-S)2]3- and L2 = [(C6H 5)PO(C6H4-2-S)2]2-), have been synthesized and characterized. The geometry of the anion in 1 can be classified to an edge-sharing bi-square-pyramid with a syn-orthogonal configuration. The one in 2 can be view as a face-sharing bioctahedron with two oxo groups in syn positions. Of note, these two complexes display intramolecular ferromagnetic interaction between two metal centers.",

author = "Tsai, {Yi Fang} and Huang, {Gui Shih} and Yang, {Chen I.} and Tsai, {Hui Lien} and Liu, {Yi Hung} and Kuo, {Ting Shen} and Hsu, {Hua Fen}",

year = "2007",

month = dec,

day = "10",

doi = "10.1021/ic7017117",

language = "English",

volume = "46",

pages = "10467--10469",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "25",

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TY - JOUR

T1 - Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers

AU - Tsai, Yi Fang

AU - Huang, Gui Shih

AU - Yang, Chen I.

AU - Tsai, Hui Lien

AU - Liu, Yi Hung

AU - Kuo, Ting Shen

AU - Hsu, Hua Fen

PY - 2007/12/10

Y1 - 2007/12/10

N2 - Two dinuclear oxovanadium(IV) thiolate complexes, [N(C5H 11)4]2-[VOL1]2 (1) and [N(C 4H9)4][(VOL2)2(μ-OCH 3)] (2) (where L1 = [(CH3)SiO(C6H 4-2-S)2]3- and L2 = [(C6H 5)PO(C6H4-2-S)2]2-), have been synthesized and characterized. The geometry of the anion in 1 can be classified to an edge-sharing bi-square-pyramid with a syn-orthogonal configuration. The one in 2 can be view as a face-sharing bioctahedron with two oxo groups in syn positions. Of note, these two complexes display intramolecular ferromagnetic interaction between two metal centers.

AB - Two dinuclear oxovanadium(IV) thiolate complexes, [N(C5H 11)4]2-[VOL1]2 (1) and [N(C 4H9)4][(VOL2)2(μ-OCH 3)] (2) (where L1 = [(CH3)SiO(C6H 4-2-S)2]3- and L2 = [(C6H 5)PO(C6H4-2-S)2]2-), have been synthesized and characterized. The geometry of the anion in 1 can be classified to an edge-sharing bi-square-pyramid with a syn-orthogonal configuration. The one in 2 can be view as a face-sharing bioctahedron with two oxo groups in syn positions. Of note, these two complexes display intramolecular ferromagnetic interaction between two metal centers.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 25

ER -

Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers

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