Dispersion of nonaqueous Co 2 Z ferrite powders with titanate coupling agent and poly(vinyl butyral)

Hsing-I Hsiang, Chih Cheng Chen, Jaw Yue Tsai

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Co 2 Z ferrite powders with the chemical composition 3Ba 0.5 Sr 0.5 O·2CoO·12Fe 2 O 3 have superior high frequency magnetic properties. However, Co 2 Z ferrite powders are difficult to apply to practical processes because of agglomeration induced by the strong magnetic attraction between particles. In this study, Co 2 Z ferrite powders pretreatment using a titanate coupling agent - neopentyl(dially)oxy tri(dioctyl)pyrophosphate titanate (Lica 38) on the sedimentation and rheological behavior is investigated. The bonding mechanisms between ferrite powder, Lica 38, and poly(vinyl butyral) (PVB) are studied using diffuse reflectance Fourier transform infrared spectroscopy is used to explain the difference in the rheological and sedimentation behaviors of untreated and titanate coupling agent-modified ferrite powders. The affinity of Co 2 Z ferrite and PVB could be substantially enhanced by coating a titanate coupling agent onto the ferrite surface. The coated layer could prevent particles from agglomeration induced by the magnetic interaction.

Original languageEnglish
Pages (from-to)252-259
Number of pages8
JournalApplied Surface Science
Volume245
Issue number1-4
DOIs
Publication statusPublished - 2005 May 30

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Coupling agents
Powders
Ferrite
Sedimentation
Agglomeration
polyvinylbutyral
Fourier transform infrared spectroscopy
Magnetic properties
Coatings
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Surfaces, Coatings and Films

Cite this

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abstract = "Co 2 Z ferrite powders with the chemical composition 3Ba 0.5 Sr 0.5 O·2CoO·12Fe 2 O 3 have superior high frequency magnetic properties. However, Co 2 Z ferrite powders are difficult to apply to practical processes because of agglomeration induced by the strong magnetic attraction between particles. In this study, Co 2 Z ferrite powders pretreatment using a titanate coupling agent - neopentyl(dially)oxy tri(dioctyl)pyrophosphate titanate (Lica 38) on the sedimentation and rheological behavior is investigated. The bonding mechanisms between ferrite powder, Lica 38, and poly(vinyl butyral) (PVB) are studied using diffuse reflectance Fourier transform infrared spectroscopy is used to explain the difference in the rheological and sedimentation behaviors of untreated and titanate coupling agent-modified ferrite powders. The affinity of Co 2 Z ferrite and PVB could be substantially enhanced by coating a titanate coupling agent onto the ferrite surface. The coated layer could prevent particles from agglomeration induced by the magnetic interaction.",
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Dispersion of nonaqueous Co 2 Z ferrite powders with titanate coupling agent and poly(vinyl butyral) . / Hsiang, Hsing-I; Chen, Chih Cheng; Tsai, Jaw Yue.

In: Applied Surface Science, Vol. 245, No. 1-4, 30.05.2005, p. 252-259.

Research output: Contribution to journalArticle

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AU - Chen, Chih Cheng

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N2 - Co 2 Z ferrite powders with the chemical composition 3Ba 0.5 Sr 0.5 O·2CoO·12Fe 2 O 3 have superior high frequency magnetic properties. However, Co 2 Z ferrite powders are difficult to apply to practical processes because of agglomeration induced by the strong magnetic attraction between particles. In this study, Co 2 Z ferrite powders pretreatment using a titanate coupling agent - neopentyl(dially)oxy tri(dioctyl)pyrophosphate titanate (Lica 38) on the sedimentation and rheological behavior is investigated. The bonding mechanisms between ferrite powder, Lica 38, and poly(vinyl butyral) (PVB) are studied using diffuse reflectance Fourier transform infrared spectroscopy is used to explain the difference in the rheological and sedimentation behaviors of untreated and titanate coupling agent-modified ferrite powders. The affinity of Co 2 Z ferrite and PVB could be substantially enhanced by coating a titanate coupling agent onto the ferrite surface. The coated layer could prevent particles from agglomeration induced by the magnetic interaction.

AB - Co 2 Z ferrite powders with the chemical composition 3Ba 0.5 Sr 0.5 O·2CoO·12Fe 2 O 3 have superior high frequency magnetic properties. However, Co 2 Z ferrite powders are difficult to apply to practical processes because of agglomeration induced by the strong magnetic attraction between particles. In this study, Co 2 Z ferrite powders pretreatment using a titanate coupling agent - neopentyl(dially)oxy tri(dioctyl)pyrophosphate titanate (Lica 38) on the sedimentation and rheological behavior is investigated. The bonding mechanisms between ferrite powder, Lica 38, and poly(vinyl butyral) (PVB) are studied using diffuse reflectance Fourier transform infrared spectroscopy is used to explain the difference in the rheological and sedimentation behaviors of untreated and titanate coupling agent-modified ferrite powders. The affinity of Co 2 Z ferrite and PVB could be substantially enhanced by coating a titanate coupling agent onto the ferrite surface. The coated layer could prevent particles from agglomeration induced by the magnetic interaction.

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