Effect of particle size on the phase behavior of block copolymer/nanoparticle composites

Chieh-Tsung Lo, Yu Cheng Chang, Shih Chi Wu, Chien Liang Lee

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Effect of particle size on the self-assembly of thiol-terminated polystyrene-stabilized Pd nanoparticles in microphase-separated block copolymers composed of poly(styrene- b-2 vinyl pyridine) (PS-PVP) was investigated using transmission electron microscopy and differential scanning calorimetry. We observe that the state of particle dispersion depends strongly on the relative size between the particle diameter (d) and PS domain spacing (D). As d/. D∼ 0.3, the self-assembly of nanoparticles in the PS domains causes swelling and increases the interfacial curvature that induces order-order transitions. At intermediate d/. D, the introduction of nanoparticles in the PS domains causes polymer stretching, resulting in the reduction of the conformational entropy. This behavior leads to the particle aggregation, which induces the macrophase separation. Additionally, these particle aggregates increase in size with increasing particle loading, and eventually they create conditions to induce disorder in the polymer morphology. As d is compatible to D, packing constraints prevent particles from assembling in the PS domains, and particles aggregate at low particle loading. This study provides valuable experimental results on the recent emerging field of nanostructured polymer nanocomposites. Our results will enable to gain better insight into the physical properties of these functional materials and will serve to validate the simulation studies of block copolymer/nanoparticle mixtures.

Original languageEnglish
Pages (from-to)6-12
Number of pages7
JournalColloids and Surfaces A: Physicochemical and Engineering Aspects
Volume368
Issue number1-3
DOIs
Publication statusPublished - 2010 Jan 1

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Phase behavior
block copolymers
Block copolymers
Particle size
Nanoparticles
nanoparticles
Polymers
composite materials
Composite materials
Self assembly
Styrene
Functional materials
Polystyrenes
Sulfhydryl Compounds
Pyridine
Stretching
Swelling
Differential scanning calorimetry
Nanocomposites
Entropy

All Science Journal Classification (ASJC) codes

  • Surfaces and Interfaces
  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

Cite this

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title = "Effect of particle size on the phase behavior of block copolymer/nanoparticle composites",
abstract = "Effect of particle size on the self-assembly of thiol-terminated polystyrene-stabilized Pd nanoparticles in microphase-separated block copolymers composed of poly(styrene- b-2 vinyl pyridine) (PS-PVP) was investigated using transmission electron microscopy and differential scanning calorimetry. We observe that the state of particle dispersion depends strongly on the relative size between the particle diameter (d) and PS domain spacing (D). As d/. D∼ 0.3, the self-assembly of nanoparticles in the PS domains causes swelling and increases the interfacial curvature that induces order-order transitions. At intermediate d/. D, the introduction of nanoparticles in the PS domains causes polymer stretching, resulting in the reduction of the conformational entropy. This behavior leads to the particle aggregation, which induces the macrophase separation. Additionally, these particle aggregates increase in size with increasing particle loading, and eventually they create conditions to induce disorder in the polymer morphology. As d is compatible to D, packing constraints prevent particles from assembling in the PS domains, and particles aggregate at low particle loading. This study provides valuable experimental results on the recent emerging field of nanostructured polymer nanocomposites. Our results will enable to gain better insight into the physical properties of these functional materials and will serve to validate the simulation studies of block copolymer/nanoparticle mixtures.",
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Effect of particle size on the phase behavior of block copolymer/nanoparticle composites. / Lo, Chieh-Tsung; Chang, Yu Cheng; Wu, Shih Chi; Lee, Chien Liang.

In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 368, No. 1-3, 01.01.2010, p. 6-12.

Research output: Contribution to journalArticle

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