Effect of temperature on the physico-chemical properties of a room temperature ionic liquid (1-Methyl-3-pentylimidazolium hexafluorophosphate) with polyethylene glycol oligomer

Tzi Yi Wu, Bor Kuan Chen, Lin Hao, Yu Chun Peng, I. Wen Sun

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

A systematic study of the effect of composition on the thermo-physical properties of the binary mixtures of 1-methyl-3-pentyl imidazolium hexafluorophosphate [MPI][PF(6)] with poly(ethylene glycol) (PEG) [M(w) = 400] is presented. The excess molar volume, refractive index deviation, viscosity deviation, and surface tension deviation values were calculated from these experimental density, ρ, refractive index, n, viscosity, η, and surface tension, γ, over the whole concentration range, respectively. The excess molar volumes are negative and continue to become increasingly negative with increasing temperature; whereas the viscosity and surface tension deviation are negative and become less negative with increasing temperature. The surface thermodynamic functions, such as surface entropy, enthalpy, as well as standard molar entropy, Parachor, and molar enthalpy of vaporization for pure ionic liquid, have been derived from the temperature dependence of the surface tension values.

Original languageEnglish
Pages (from-to)2598-2617
Number of pages20
JournalInternational journal of molecular sciences
Volume12
Issue number4
DOIs
Publication statusPublished - 2011

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Molecular Biology
  • Spectroscopy
  • Computer Science Applications
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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