Effects of film treatment on the performance of poly(3-hexylthiophene)/soluble fullerene-based organic solar cells

Tzung Fang Guo, Ten Chin Wen, Georgi L'vovich Pakhomov, Xing Guo Chin, Siou Hong Liou, Pei Hong Yeh, Cheng Hsien Yang

Research output: Contribution to journalArticlepeer-review

68 Citations (Scopus)

Abstract

This work investigates the correlations between the morphological characteristics of the active layers, comprised of poly(3-hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester, and the photovoltaic performance of polymer-based solar cells. The active layers were deposited by spin-coating the polymer solutions under various conditions and, then, characterized by atomic force microscopy, X-ray diffraction, UV/Vis and Raman spectroscopy. Results of this study indicate that solar cells employing the slow-solvent-vapor-treatment blend films as the active layers exhibit the enhanced power conversion efficiency (3.0%), short-circuit (8.71 mA/cm2) current and fill factor (0.59) than that of as-cast and fast-thermal-annealing blend films.

Original languageEnglish
Pages (from-to)3138-3142
Number of pages5
JournalThin Solid Films
Volume516
Issue number10
DOIs
Publication statusPublished - 2008 Mar 31

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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