Effects of TiCl3-decorated MWCNTs addition on the dehydrogenation behavior and stability of LiAlH4

Chia Yen Tan, Wen Ta Tsai

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10 Citations (Scopus)

Abstract

A complex catalyst for enhancing the dehydrogenation kinetics of LiAlH4 was developed by using an impregnation process to decorate TiCl3 on multiwall carbon nanotubes (MWCNTs). The effects of these composite catalysts on the dehydrogenation behavior were investigated by using thermal gravimetric analysis (TGA) and in-situ synchrotron X-ray diffraction (XRD) technique. The experimental results showed that the initial dehydrogenation temperature could be lowered by adding the appropriate amount of TiCl3-MWCNTs composite. LiAlH4 became unstable and decomposed even at room temperature when 20 wt% TiCl3-MWCNTs was added.

Original languageEnglish
Pages (from-to)20038-20044
Number of pages7
JournalInternational Journal of Hydrogen Energy
Volume39
Issue number35
DOIs
Publication statusPublished - 2014 Dec 3

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

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