Efficient and selective oxidation of primary and secondary alcohols using an iron(III)/phenanthroline complex: Structural studies and catalytic activity

Bhaskar Biswas; Afnan Al-Hunaiti; Minna T. Räisänen; Simone Ansalone; Markku Leskelä; Timo Repo; Yen Tung Chen; Hui-Lien Tsai; Anil D. Naik; Antoine P. Railliet; Yann Garcia; Rajarshi Ghosh; Niranjan Kole

doi:10.1002/ejic.201200658

Efficient and selective oxidation of primary and secondary alcohols using an iron(III)/phenanthroline complex: Structural studies and catalytic activity

Bhaskar Biswas, Afnan Al-Hunaiti, Minna T. Räisänen, Simone Ansalone, Markku Leskelä, Timo Repo, Yen Tung Chen, Hui-Lien Tsai, Anil D. Naik, Antoine P. Railliet, Yann Garcia, Rajarshi Ghosh, Niranjan Kole

Department of Chemistry

Research output: Contribution to journal › Article

55 Citations (Scopus)

Abstract

An efficient catalytic system for the oxidation of alcohols has been developed by using iron(III) catalyst [Fe(phen) ₂Cl ₂]NO ₃ (1) (phen = 1,10-phenanthroline) and H ₂O ₂ as terminal oxidant. A series of primary and secondary alcohols were oxidized into aldehydes and ketones in good yields and excellent selectivities after a short reaction time. The mononuclear iron(III) complex [Fe(phen) ₂Cl ₂]NO ₃ was characterized by several independent methods. The X-ray structure shows distorted octahedral geometry around the Fe ^III center, which is in a high-spin state (S = 5/2) according to Mössbauer study.

Original language	English
Pages (from-to)	4479-4485
Number of pages	7
Journal	European Journal of Inorganic Chemistry
Issue number	28
DOIs	https://doi.org/10.1002/ejic.201200658
Publication status	Published - 2012 Oct 1

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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Biswas, B., Al-Hunaiti, A., Räisänen, M. T., Ansalone, S., Leskelä, M., Repo, T., Chen, Y. T., Tsai, H-L., Naik, A. D., Railliet, A. P., Garcia, Y., Ghosh, R., & Kole, N. (2012). Efficient and selective oxidation of primary and secondary alcohols using an iron(III)/phenanthroline complex: Structural studies and catalytic activity. European Journal of Inorganic Chemistry, (28), 4479-4485. https://doi.org/10.1002/ejic.201200658

Biswas, Bhaskar ; Al-Hunaiti, Afnan ; Räisänen, Minna T. ; Ansalone, Simone ; Leskelä, Markku ; Repo, Timo ; Chen, Yen Tung ; Tsai, Hui-Lien ; Naik, Anil D. ; Railliet, Antoine P. ; Garcia, Yann ; Ghosh, Rajarshi ; Kole, Niranjan. / Efficient and selective oxidation of primary and secondary alcohols using an iron(III)/phenanthroline complex : Structural studies and catalytic activity. In: European Journal of Inorganic Chemistry. 2012 ; No. 28. pp. 4479-4485.

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title = "Efficient and selective oxidation of primary and secondary alcohols using an iron(III)/phenanthroline complex: Structural studies and catalytic activity",

abstract = "An efficient catalytic system for the oxidation of alcohols has been developed by using iron(III) catalyst [Fe(phen) 2Cl 2]NO 3 (1) (phen = 1,10-phenanthroline) and H 2O 2 as terminal oxidant. A series of primary and secondary alcohols were oxidized into aldehydes and ketones in good yields and excellent selectivities after a short reaction time. The mononuclear iron(III) complex [Fe(phen) 2Cl 2]NO 3 was characterized by several independent methods. The X-ray structure shows distorted octahedral geometry around the Fe III center, which is in a high-spin state (S = 5/2) according to M{\"o}ssbauer study.",

author = "Bhaskar Biswas and Afnan Al-Hunaiti and R{\"a}is{\"a}nen, {Minna T.} and Simone Ansalone and Markku Leskel{\"a} and Timo Repo and Chen, {Yen Tung} and Hui-Lien Tsai and Naik, {Anil D.} and Railliet, {Antoine P.} and Yann Garcia and Rajarshi Ghosh and Niranjan Kole",

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doi = "10.1002/ejic.201200658",

language = "English",

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Biswas, B, Al-Hunaiti, A, Räisänen, MT, Ansalone, S, Leskelä, M, Repo, T, Chen, YT, Tsai, H-L, Naik, AD, Railliet, AP, Garcia, Y, Ghosh, R & Kole, N 2012, 'Efficient and selective oxidation of primary and secondary alcohols using an iron(III)/phenanthroline complex: Structural studies and catalytic activity', European Journal of Inorganic Chemistry, no. 28, pp. 4479-4485. https://doi.org/10.1002/ejic.201200658

Efficient and selective oxidation of primary and secondary alcohols using an iron(III)/phenanthroline complex : Structural studies and catalytic activity. / Biswas, Bhaskar; Al-Hunaiti, Afnan; Räisänen, Minna T.; Ansalone, Simone; Leskelä, Markku; Repo, Timo; Chen, Yen Tung; Tsai, Hui-Lien; Naik, Anil D.; Railliet, Antoine P.; Garcia, Yann; Ghosh, Rajarshi; Kole, Niranjan.

In: European Journal of Inorganic Chemistry, No. 28, 01.10.2012, p. 4479-4485.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Efficient and selective oxidation of primary and secondary alcohols using an iron(III)/phenanthroline complex

T2 - Structural studies and catalytic activity

AU - Biswas, Bhaskar

AU - Al-Hunaiti, Afnan

AU - Räisänen, Minna T.

AU - Ansalone, Simone

AU - Leskelä, Markku

AU - Repo, Timo

AU - Chen, Yen Tung

AU - Tsai, Hui-Lien

AU - Naik, Anil D.

AU - Railliet, Antoine P.

AU - Garcia, Yann

AU - Ghosh, Rajarshi

AU - Kole, Niranjan

PY - 2012/10/1

Y1 - 2012/10/1

N2 - An efficient catalytic system for the oxidation of alcohols has been developed by using iron(III) catalyst [Fe(phen) 2Cl 2]NO 3 (1) (phen = 1,10-phenanthroline) and H 2O 2 as terminal oxidant. A series of primary and secondary alcohols were oxidized into aldehydes and ketones in good yields and excellent selectivities after a short reaction time. The mononuclear iron(III) complex [Fe(phen) 2Cl 2]NO 3 was characterized by several independent methods. The X-ray structure shows distorted octahedral geometry around the Fe III center, which is in a high-spin state (S = 5/2) according to Mössbauer study.

AB - An efficient catalytic system for the oxidation of alcohols has been developed by using iron(III) catalyst [Fe(phen) 2Cl 2]NO 3 (1) (phen = 1,10-phenanthroline) and H 2O 2 as terminal oxidant. A series of primary and secondary alcohols were oxidized into aldehydes and ketones in good yields and excellent selectivities after a short reaction time. The mononuclear iron(III) complex [Fe(phen) 2Cl 2]NO 3 was characterized by several independent methods. The X-ray structure shows distorted octahedral geometry around the Fe III center, which is in a high-spin state (S = 5/2) according to Mössbauer study.

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