Efficient ion transport in activated carbon capacitors assembled with gelled polymer electrolytes based on poly(ethylene oxide) cured with poly(propylene oxide) diamines

Chien Pin Tien, Hsisheng Teng

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

The beneficial feature of the polymeric framework in a gel electrolyte is to assist ion transport via the segmental motion of the polymer chains. This feature was displayed by ac impedance analysis on an activated carbon capacitor assembled with a gel electrolyte, which consisted of poly(ethylene oxide)-co-poly(propylene oxide) as a host, propylene carbonate (PC) as a plasticizer, and LiClO4 as an electrolytic salt. A smaller resistance was found for the cell assembled with the gel electrolyte relative to that for a cell with a LiClO4/PC liquid electrolyte, even if the gel and liquid electrolytes had similar conductivities. It is suggested that the polymer chains enhanced the contact between the electrolyte and carbon surface and promoted ion transport through the concentration-graded solvent channel near the interface. The polymer-assisted transport also led to more efficient ion diffusion inside carbon micropores. Constant phase element analysis of the capacitive behavior in micropores showed that the presence of polymer chains did not affect the surface characteristic for double layer formation. This developed gel electrolyte promoted the power performance of activated carbon electrodes by enhancing the transport of electrolyte ions inside and outside the micropores.

Original languageEnglish
Pages (from-to)452-456
Number of pages5
JournalJournal of the Taiwan Institute of Chemical Engineers
Volume40
Issue number4
DOIs
Publication statusPublished - 2009 Jul 1

Fingerprint

Polypropylene oxides
Diamines
Polyethylene oxides
Activated carbon
Electrolytes
Polymers
Capacitors
Ions
Gels
UCON 50-HB-5100
Propylene
Carbonates
Carbon
Plasticizers
polypropylene glycol
Liquids
Chemical elements
Salts
Electrodes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

@article{eadc2b37b4524b538c75afbeca19c9d8,
title = "Efficient ion transport in activated carbon capacitors assembled with gelled polymer electrolytes based on poly(ethylene oxide) cured with poly(propylene oxide) diamines",
abstract = "The beneficial feature of the polymeric framework in a gel electrolyte is to assist ion transport via the segmental motion of the polymer chains. This feature was displayed by ac impedance analysis on an activated carbon capacitor assembled with a gel electrolyte, which consisted of poly(ethylene oxide)-co-poly(propylene oxide) as a host, propylene carbonate (PC) as a plasticizer, and LiClO4 as an electrolytic salt. A smaller resistance was found for the cell assembled with the gel electrolyte relative to that for a cell with a LiClO4/PC liquid electrolyte, even if the gel and liquid electrolytes had similar conductivities. It is suggested that the polymer chains enhanced the contact between the electrolyte and carbon surface and promoted ion transport through the concentration-graded solvent channel near the interface. The polymer-assisted transport also led to more efficient ion diffusion inside carbon micropores. Constant phase element analysis of the capacitive behavior in micropores showed that the presence of polymer chains did not affect the surface characteristic for double layer formation. This developed gel electrolyte promoted the power performance of activated carbon electrodes by enhancing the transport of electrolyte ions inside and outside the micropores.",
author = "Tien, {Chien Pin} and Hsisheng Teng",
year = "2009",
month = "7",
day = "1",
doi = "10.1016/j.jtice.2008.11.005",
language = "English",
volume = "40",
pages = "452--456",
journal = "Journal of the Taiwan Institute of Chemical Engineers",
issn = "1876-1070",
publisher = "Taiwan Institute of Chemical Engineers",
number = "4",

}

TY - JOUR

T1 - Efficient ion transport in activated carbon capacitors assembled with gelled polymer electrolytes based on poly(ethylene oxide) cured with poly(propylene oxide) diamines

AU - Tien, Chien Pin

AU - Teng, Hsisheng

PY - 2009/7/1

Y1 - 2009/7/1

N2 - The beneficial feature of the polymeric framework in a gel electrolyte is to assist ion transport via the segmental motion of the polymer chains. This feature was displayed by ac impedance analysis on an activated carbon capacitor assembled with a gel electrolyte, which consisted of poly(ethylene oxide)-co-poly(propylene oxide) as a host, propylene carbonate (PC) as a plasticizer, and LiClO4 as an electrolytic salt. A smaller resistance was found for the cell assembled with the gel electrolyte relative to that for a cell with a LiClO4/PC liquid electrolyte, even if the gel and liquid electrolytes had similar conductivities. It is suggested that the polymer chains enhanced the contact between the electrolyte and carbon surface and promoted ion transport through the concentration-graded solvent channel near the interface. The polymer-assisted transport also led to more efficient ion diffusion inside carbon micropores. Constant phase element analysis of the capacitive behavior in micropores showed that the presence of polymer chains did not affect the surface characteristic for double layer formation. This developed gel electrolyte promoted the power performance of activated carbon electrodes by enhancing the transport of electrolyte ions inside and outside the micropores.

AB - The beneficial feature of the polymeric framework in a gel electrolyte is to assist ion transport via the segmental motion of the polymer chains. This feature was displayed by ac impedance analysis on an activated carbon capacitor assembled with a gel electrolyte, which consisted of poly(ethylene oxide)-co-poly(propylene oxide) as a host, propylene carbonate (PC) as a plasticizer, and LiClO4 as an electrolytic salt. A smaller resistance was found for the cell assembled with the gel electrolyte relative to that for a cell with a LiClO4/PC liquid electrolyte, even if the gel and liquid electrolytes had similar conductivities. It is suggested that the polymer chains enhanced the contact between the electrolyte and carbon surface and promoted ion transport through the concentration-graded solvent channel near the interface. The polymer-assisted transport also led to more efficient ion diffusion inside carbon micropores. Constant phase element analysis of the capacitive behavior in micropores showed that the presence of polymer chains did not affect the surface characteristic for double layer formation. This developed gel electrolyte promoted the power performance of activated carbon electrodes by enhancing the transport of electrolyte ions inside and outside the micropores.

UR - http://www.scopus.com/inward/record.url?scp=67349148330&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67349148330&partnerID=8YFLogxK

U2 - 10.1016/j.jtice.2008.11.005

DO - 10.1016/j.jtice.2008.11.005

M3 - Article

AN - SCOPUS:67349148330

VL - 40

SP - 452

EP - 456

JO - Journal of the Taiwan Institute of Chemical Engineers

JF - Journal of the Taiwan Institute of Chemical Engineers

SN - 1876-1070

IS - 4

ER -