Electrochemical copolymerization of 1-naphthylamine with aniline and o-toluidine

C. Y. Chung, T. C. Wen, A. Gopalan

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

Copolymers of 1-naphthylamine (NPA) with aniline (ANI) and o-toluidine (OT) were deposited on platinum electrode in 1M perchloric acid (HClO4) through cyclic voltammetry. The cyclic voltammograms of the copolymer showed a dominant redox couple at a midpoint potential of ca. 0.38 V with a peak separation ranging from 40 to 100 mV. Copolymerization was found to be possible only at low NPA to ANI or OT ratio. UV-visible spectroelectrochemical study on the copolymer films prepared using different feed ratios of NPA revealed the presence of NPA units in varying proportion in the copolymer. The copolymers possess both electrochemical and spectroelectrochemical properties of PNPA and PANI/POT.

Original languageEnglish
Pages (from-to)148-154
Number of pages7
JournalMaterials Chemistry and Physics
Volume71
Issue number2
DOIs
Publication statusPublished - 2001 Aug 15

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Electrochemical copolymerization of 1-naphthylamine with aniline and o-toluidine'. Together they form a unique fingerprint.

Cite this