Electrochemical copolymerization of aniline and 2,2′-dithiodianiline

Li Ming Huang, Ten Chin Wen, Chien Hsin Yang

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Copolymerization of 2,2′-dithiodianiline (DTDA) and aniline (An) was performed electrochemically by cyclic voltammetry on Pt electrode in 1M HCl. The copolymerization rate is strongly dependent on the amount of DTDA in the comonomer feed. The composition of the copolymeric films were determined by X-ray photoelectron spectroscopy (XPS) and were controlled by changing comonomer feed ratios. The fraction of DTDA units in the copolymers is proportional to the fraction of DTDA in the comonomer feeds. The reactivity of An decreases by increasing the amount of DTDA in the comonomer feed. Scanning electron microscopy (SEM) photographs show that there exist clear differences in morphology of the polymer films at various DTDA concentrations.

Original languageEnglish
Pages (from-to)434-441
Number of pages8
JournalMaterials Chemistry and Physics
Volume77
Issue number2
DOIs
Publication statusPublished - 2003 Jan 15

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Electrochemical copolymerization of aniline and 2,2′-dithiodianiline'. Together they form a unique fingerprint.

  • Cite this