Electrochemical Copolymerization of Diphenylamine and Anthranilic Acid with Various Feed Ratios

Ming Sieng Wu, Ten Chin Wen, A. Gopalan

Research output: Contribution to journalArticlepeer-review

51 Citations (Scopus)

Abstract

Electrochemical copolymerization of diphenylamine (DPA) with anthranilic acid (AA) was performed in aqueous 4 M H2SO4 solution for different feed ratios of DPA using cyclic voltammetry. The copolymer film was grown for different numbers of cycles, Cn, and feed ratios of DPA. Electrochemical homopolymerization of DPA was also carried out under identical conditions and compared. A growth equation of the deposited films in terms of concentrations of DPA and AA and Cn is deduced as QG = k[DPA]2.0[AA] 0.2C1.2n by utilizing the charge associated for film deposition. The copolymer compositions were determined by X-ray photoelectron spectroscopy. Reactivity ratios of DPA and AA were computed by using Fineman-Ross and Kelen-Tüdös methods.

Original languageEnglish
Pages (from-to)D65-D73
JournalJournal of the Electrochemical Society
Volume148
Issue number5
DOIs
Publication statusPublished - 2001 May

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Electrochemical Copolymerization of Diphenylamine and Anthranilic Acid with Various Feed Ratios'. Together they form a unique fingerprint.

Cite this