@article{943e09a2039c4b9ca441653970de745f,
title = "Electrochemical Evolution of Pore-Confined Metallic Molybdenum in a Metal-Organic Framework (MOF) for All-MOF-Based Pseudocapacitors",
abstract = "In this study, metallic molybdenum nanoparticles confined in the nanopores of a zirconium-based MOF (Zr-MOF), MOF-808, are prepared by a self-limiting decoration of spatially isolated Mo(VI) sites on the hexa-zirconium nodes of MOF-808, followed by the electrochemical reduction of Mo(VI) to metallic Mo. The obtained pore-confined Mo exhibits reversible redox activity in a neutral aqueous electrolyte and serves as the pseudocapacitive material for negative electrodes. By introducing another MOF-based pseudocapacitive material that can be used for positive electrodes, a manganese-decorated Zr-MOF-carbon nanotube nanocomposite, as a demonstration, all-Zr-MOF-based asymmetric pseudocapacitors with an aqueous electrolyte are fabricated.",
author = "Li, {Jun Hong} and Chen, {Yu Chuan} and Wang, {Yi Sen} and Ho, {Wei Huan} and Gu, {Yu Juan} and Chuang, {Cheng Hsun} and Song, {Yi Da} and Kung, {Chung Wei}",
note = "Funding Information: This work was sponsored by the Ministry of Science and Technology (MOST) of Taiwan, under projects MOST 107-2218-E-006-054-MY3. We also thank the support from the Yushan Young Scholar Program, under Ministry of Education (MOE), Taiwan. This article was also supported in part by Higher Education Sprout Project, MOE, Taiwan, to the Headquarters of University Advancement at National Cheng Kung University. We also thank the support from Formosa Plastics Group, Taiwan. We thank Dr. Wen-Shuo Chuang and Prof. Chih-Yen Chen in the Department of Material Science and Optoelectronic Engineering, National Sun Yat-Sen University, Kaohsiung City, Taiwan, for the STEM experiments. We also thank the Surface Analysis Lab in the Department of Chemical Engineering, National Taiwan University, for measuring XPS spectra. Publisher Copyright: Copyright {\textcopyright} 2020 American Chemical Society.",
year = "2020",
month = jul,
day = "27",
doi = "10.1021/acsaem.0c00399",
language = "English",
volume = "3",
pages = "6258--6267",
journal = "ACS Applied Energy Materials",
issn = "2574-0962",
publisher = "American Chemical Society",
number = "7",
}