Electrochemical preparation of porous copper surfaces in zinc chloride-1-ethyl-3-methyl imidazolium chloride ionic liquid

Yi Wen Lin, Chia Cheng Tai, I. Wen Sun

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

The preparation of porous copper or copper-zinc surfaces by electrochemical formation of binary Cu-Zn alloys on Cu substrate and subsequent electrochemical etching of the zinc was investigated in a zinc chloride-1-ethyl-3- methylimidazolium chloride ionic liquid at 120°C. Cyclic voltammetry and X-ray diffraction measurements suggested that phase transformation from γ - to Β′ - Cu-Zn alloy occurred during constant potential dealloying. Essentially all the Zn content in the Cu-Zn could be removed from the alloy with dealloying at a sufficiently positive potential. Dealloyed materials exhibited well-developed bicontinuous porous structure. The dependence of the surface morphology of the porous Cu film on several experimental parameters, including deposition current and charge, and anodizing potential and temperature, were examined.

Original languageEnglish
Pages (from-to)D316-D321
JournalJournal of the Electrochemical Society
Volume154
Issue number6
DOIs
Publication statusPublished - 2007 Aug 1

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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