Electrochemistry of osmium (III) and -(IV) chloride complexes in the basic aluminum chloride-1 -Methyl-3-ethylimidazolium chloride ionic liquid

I. Wen Sun, Edmund H. Ward, Charles L. Hussey

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The electrolytic reduction of [OsCl6]2- in the basic aluminum chloride-1-methyl-3-ethylimidazolium chloride (AlCl3-MeEtimCl) room temperature ionic liquid produces [OsCl6]3-. The [OsCl6]2- + e- ⇌[OsCl6]3- electrode reaction exhibits reversible behavior at a glassy carbon electrode in this solvent and appears reversible at this electrode in pure molten MeEtimCl at 103°C as well. The formal electrode potential for this redox system in the 49.0/51.0 mole percent (m/o) AlCl3-MeEtimCl melt is approximately -0.31V vs. Al in the 66.7/33.3 m/o ionic liquid. The average Stokes-Einstein products for the [OsCl6]2- and [OsCl6]3- ions are 6.6 x 10-8 and 4.7 x 10–8 g cm s-2, respectively, at 40°C and are slightly larger than those previously found for the corresponding iridium complexes. Absorption spectra for [OsCl6]2- and [OsCl6]3- in basic AlCl3-MeEtimCl are similar to the spectra of these complexes in aqueous HC1 solution, but seem to be less distorted. Molar absorptivities for the [OsCl6]3- ion are reported for the first time.

Original languageEnglish
Pages (from-to)3035-3038
Number of pages4
JournalJournal of the Electrochemical Society
Volume135
Issue number12
DOIs
Publication statusPublished - 1988 Dec

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Electrochemistry of osmium (III) and -(IV) chloride complexes in the basic aluminum chloride-1 -Methyl-3-ethylimidazolium chloride ionic liquid'. Together they form a unique fingerprint.

Cite this