Electrochromic Nb-doped WO 3 films: Effects of post annealing

Chun Kai Wang, Diptiranjan Sahu, Sheng Chang Wang, Jow Lay Huang

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

The Nb-doped WO 3 films were deposited by e-beam co-evaporation method using ceramic WO 3 targets and metal Nb slugs. The films were analyzed by glancing incident angle X-ray diffraction (GIAXRD), UV/visible spectrophotometer, electrochemical cyclic voltammetry, X-ray photoelectron spectroscopy (XPS). The as-prepared film is brown and amorphous in structure. The film has low transmission in optical visible region. The XPS results indicate that the as-deposited film is non-stoichiometric. By applying a negative potential, the as-deposited film does not show obvious electrochromic effect. However, the electrochromic properties of Nb-doped WO 3 films are improved by post annealing treatment at 350, 400, and 450 °C in oxygen atmosphere. The Nb-doped WO 3 films transform into crystalline structure and become transparent after post annealing treatment. The energy band gap, optical modulation, and color efficiency increase with annealing temperature.

Original languageEnglish
Pages (from-to)2829-2833
Number of pages5
JournalCeramics International
Volume38
Issue number4
DOIs
Publication statusPublished - 2012 May

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

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