Electrocoagulation of tetrafluoroborate (BF4) and the derived boron and fluorine using aluminum electrodes

Jui Yen Lin, Agnes Raharjo, Li Hsin Hsu, Yu Jen Shih, Yao Hui Huang

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Tetrafluoroborate anion (BF4) is found in the streams of flue-gas desulfurization and borosilicate glasses etching which deteriorates water quality through slow hydrolysis into boric acid and fluoride. Decomposition and electrocoagulation (EC) of BF4 were studied using metallic aluminum as the sacrificial electrode. The dissolved Al(III) from the anode could efficiently decompose BF4 in forms of fluoroaluminate complexes, and the derived boric acid and fluoride ion were removed by sweep flocculation. Major variables were investigated to optimize EC, including the reaction pH, initial concentration of BF4, current density and electrolyte type. The mechanism of EC process was elucidated with the kinetics of consecutive reactions. Experimental results suggested that the removal of BF4 and total fluoride were less influenced by pH, and that of total boron reached a maximum at pH 8 which favored the surface complexation between borate species and EC precipitates. Under the conditions: [BF4]0 = 9.3 mM, [NaCl] = 10 mM, pH = 8.0, current density = 5 mA/cm2, 98.3% of BF4 was decomposed and the removal of total fluoride and boron attained 98.2% and 74.1%, respectively within 3 h. EC using the Al electrode outperformed the conventional chemical coagulation and reduced the levels of BF4–], B(OH)3 and F in aqueous solution synergically.

Original languageEnglish
Pages (from-to)362-371
Number of pages10
JournalWater Research
Volume155
DOIs
Publication statusPublished - 2019 May 15

Fingerprint

Boric acid
fluorine
Fluorine
boron
fluoride
Boron
electrode
Current density
aluminum
Aluminum
Electrodes
Borosilicate glass
Flocculation
Desulfurization
Coagulation
Complexation
density current
Flue gases
Water quality
Precipitates

All Science Journal Classification (ASJC) codes

  • Ecological Modelling
  • Water Science and Technology
  • Waste Management and Disposal
  • Pollution

Cite this

Lin, Jui Yen ; Raharjo, Agnes ; Hsu, Li Hsin ; Shih, Yu Jen ; Huang, Yao Hui. / Electrocoagulation of tetrafluoroborate (BF4) and the derived boron and fluorine using aluminum electrodes. In: Water Research. 2019 ; Vol. 155. pp. 362-371.
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abstract = "Tetrafluoroborate anion (BF4−) is found in the streams of flue-gas desulfurization and borosilicate glasses etching which deteriorates water quality through slow hydrolysis into boric acid and fluoride. Decomposition and electrocoagulation (EC) of BF4− were studied using metallic aluminum as the sacrificial electrode. The dissolved Al(III) from the anode could efficiently decompose BF4− in forms of fluoroaluminate complexes, and the derived boric acid and fluoride ion were removed by sweep flocculation. Major variables were investigated to optimize EC, including the reaction pH, initial concentration of BF4−, current density and electrolyte type. The mechanism of EC process was elucidated with the kinetics of consecutive reactions. Experimental results suggested that the removal of BF4− and total fluoride were less influenced by pH, and that of total boron reached a maximum at pH 8 which favored the surface complexation between borate species and EC precipitates. Under the conditions: [BF4−]0 = 9.3 mM, [NaCl] = 10 mM, pH = 8.0, current density = 5 mA/cm2, 98.3{\%} of BF4− was decomposed and the removal of total fluoride and boron attained 98.2{\%} and 74.1{\%}, respectively within 3 h. EC using the Al electrode outperformed the conventional chemical coagulation and reduced the levels of BF4–], B(OH)3 and F− in aqueous solution synergically.",
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Electrocoagulation of tetrafluoroborate (BF4) and the derived boron and fluorine using aluminum electrodes. / Lin, Jui Yen; Raharjo, Agnes; Hsu, Li Hsin; Shih, Yu Jen; Huang, Yao Hui.

In: Water Research, Vol. 155, 15.05.2019, p. 362-371.

Research output: Contribution to journalArticle

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T1 - Electrocoagulation of tetrafluoroborate (BF4−) and the derived boron and fluorine using aluminum electrodes

AU - Lin, Jui Yen

AU - Raharjo, Agnes

AU - Hsu, Li Hsin

AU - Shih, Yu Jen

AU - Huang, Yao Hui

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