Electrode properties of La1-xSrxCuO 2.5-δ as new cathode materials for intermediate-temperature SOFCs

Ho Chieh Yu, Kuan Zong Fung

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51 Citations (Scopus)

Abstract

Oxygen-deficient perovskite type oxides La1-xSr xCuO2.5-δ (LSCu) have been synthesized in the composition range: 0.15≤x≤0.3. Due to their high oxygen vacancy concentration and good electrical conductivity, these materials are characterized as new positive electrode (cathode) materials for intermediate-temperature solid oxide fuel cells (IT-SOFCs). The valence state of copper ions, thermal expansion, cathodic overpotential, reactivity with yttria-stabilized zirconia (YSZ) and polarization resistance (Rp) of the LSCu|YSZ interface are examined. At 800°C, the sample with the composition of La0.7Sr0.3CuO2.5-δ exhibits the lowest overpotential of about 10 and 12.6mV at a current density of 150 and 200mAcm-2, respectively. LSCu show no reaction against yttria-stabilized zirconia (8YSZ) at 800°C for 1000h. Reaction between LSCu and YSZ occurs, however, at 900°C for 10h. The formation of SrZrO 3 is observed. Based on the results of ac impedance analyses, the polarization resistance of LSCu decreases from 0.85 to 0.25Ω at 800°C when the fraction of Sr is increased from 20 to 30%. The reduction of polarization resistance is improved by the presence of oxygen vacancies in LSCu. These oxygen vacancies provide numerous pathways for the diffusion of oxygen ions electrode surface to the triple phase boundary (TPB) and the electrode|electrolyte interface. Therefore, LSCu may be a very attractive cathode material for IT-SOFCs.

Original languageEnglish
Pages (from-to)162-168
Number of pages7
JournalJournal of Power Sources
Volume133
Issue number2
DOIs
Publication statusPublished - 2004 Jun 4

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

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