Electrodeposition of distinct one-dimensional Zn biaxial microbelt from the zinc chloride-1-ethyl-3-methylidazolium chloride ionic liquid

Jia Ming Yang; Yi Ting Hsieh; Tzu Tsang Chu-Tien; I. Wen Sun

doi:10.1149/1.3559459

Electrodeposition of distinct one-dimensional Zn biaxial microbelt from the zinc chloride-1-ethyl-3-methylidazolium chloride ionic liquid

Jia Ming Yang, Yi Ting Hsieh, Tzu Tsang Chu-Tien, I. Wen Sun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The application of ionic liquids as versatile media for electrochemical preparation of one-dimensional metal structures is demonstrated by the electrocrystallization of non-tangled, straight Zn biaxial microbelt without using any template from a Lewis acidic chlorozincate ionic liquid containing 36.0-64.0 mol Zinc Chloride-1-Ethyl-3-methylidazolium Chloride at 110C. Each Zn biaxial microbelt has the morphology similar to that formed by folding a ∼100 nm thick straight ribbon along its central axis to produce a unique V shaped cross-sectional view that has not been observed for Zn wires prepared electrochemically in other media.

Original language	English
Pages (from-to)	D235-D239
Journal	Journal of the Electrochemical Society
Volume	158
Issue number	5
DOIs	https://doi.org/10.1149/1.3559459
Publication status	Published - 2011 Apr 4

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films
Electrochemistry
Materials Chemistry

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AU - Yang, Jia Ming

AU - Hsieh, Yi Ting

AU - Chu-Tien, Tzu Tsang

AU - Sun, I. Wen

PY - 2011/4/4

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N2 - The application of ionic liquids as versatile media for electrochemical preparation of one-dimensional metal structures is demonstrated by the electrocrystallization of non-tangled, straight Zn biaxial microbelt without using any template from a Lewis acidic chlorozincate ionic liquid containing 36.0-64.0 mol Zinc Chloride-1-Ethyl-3-methylidazolium Chloride at 110C. Each Zn biaxial microbelt has the morphology similar to that formed by folding a ∼100 nm thick straight ribbon along its central axis to produce a unique V shaped cross-sectional view that has not been observed for Zn wires prepared electrochemically in other media.

AB - The application of ionic liquids as versatile media for electrochemical preparation of one-dimensional metal structures is demonstrated by the electrocrystallization of non-tangled, straight Zn biaxial microbelt without using any template from a Lewis acidic chlorozincate ionic liquid containing 36.0-64.0 mol Zinc Chloride-1-Ethyl-3-methylidazolium Chloride at 110C. Each Zn biaxial microbelt has the morphology similar to that formed by folding a ∼100 nm thick straight ribbon along its central axis to produce a unique V shaped cross-sectional view that has not been observed for Zn wires prepared electrochemically in other media.

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Electrodeposition of distinct one-dimensional Zn biaxial microbelt from the zinc chloride-1-ethyl-3-methylidazolium chloride ionic liquid

Abstract

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