Enhanced conductivity of plasticized polymer electrolytes containing chelating groups

Yu Hao Liang, Chi Yuan Hung, Cheng Chien Wang, Chuh Yung Chen

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Poly(AN-co-GMA-IDA) has been prepared by copolymerizing acrylonitrile (AN) and 2-methylacrylic acid 3-(bis-carboxymethylamino-2-hydroxy-propyl ester) (GMA-IDA). The polymers were mixed with the plasticizer ethylene carbonate (EC) and lithium perchlorate (LiClO4) to form gel polymer electrolytes (GPE). Fourier-transform infrared spectroscopy (FT-IR) has revealed that the GMA-IDA unit can improve the dissociation of the lithium salt. Furthermore, the GMA-IDA can hinder the crystallization of EC, thereby improving the conductivity of the GPE. This has been established by differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analysis. The interaction between GMA-IDA and EC has been confirmed by FT-IR and 7Li solid-state NMR. The maximum conductivity measured in this investigation was 9.75 × 10-4 S cm-1. Crown

Original languageEnglish
Pages (from-to)261-267
Number of pages7
JournalJournal of Power Sources
Volume188
Issue number1
DOIs
Publication statusPublished - 2009 Mar 1

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

Fingerprint Dive into the research topics of 'Enhanced conductivity of plasticized polymer electrolytes containing chelating groups'. Together they form a unique fingerprint.

  • Cite this