Enhanced decomposition of NO on the alkalized PdO/Al2O3 catalyst

Y. J. Huang; H. Paul Wang; Chuin Tih Yeh; C. C. Tai; C. Y. Peng

doi:10.1016/S0045-6535(99)00151-4

Enhanced decomposition of NO on the alkalized PdO/Al₂O₃ catalyst

Y. J. Huang, H. Paul Wang, Chuin Tih Yeh, C. C. Tai, C. Y. Peng

Department of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Experimentally, decomposition of NO on the alkalized Pd/Al₂O₃ catalyst is remarkably enhanced at 825-1000 K. The enhancement in N₂ yield may be due to the additional basic sites on the alkalized catalyst that can trap NO molecules. However, at T > 1000 K, due to the fact that the absorbed oxygen in subsurface or bulk of Pd was involved in the formation and desorption of oxygen molecules, yield of oxygen was enhanced.

Original language	English
Pages (from-to)	2279-2287
Number of pages	9
Journal	Chemosphere
Volume	39
Issue number	13
DOIs	https://doi.org/10.1016/S0045-6535(99)00151-4
Publication status	Published - 1999 Dec

All Science Journal Classification (ASJC) codes

Environmental Engineering
Environmental Chemistry
Chemistry(all)
Pollution
Health, Toxicology and Mutagenesis

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10.1016/S0045-6535(99)00151-4

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abstract = "Experimentally, decomposition of NO on the alkalized Pd/Al2O3 catalyst is remarkably enhanced at 825-1000 K. The enhancement in N2 yield may be due to the additional basic sites on the alkalized catalyst that can trap NO molecules. However, at T > 1000 K, due to the fact that the absorbed oxygen in subsurface or bulk of Pd was involved in the formation and desorption of oxygen molecules, yield of oxygen was enhanced.",

author = "Huang, {Y. J.} and Wang, {H. Paul} and Yeh, {Chuin Tih} and Tai, {C. C.} and Peng, {C. Y.}",

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AU - Huang, Y. J.

AU - Wang, H. Paul

AU - Yeh, Chuin Tih

AU - Tai, C. C.

AU - Peng, C. Y.

PY - 1999/12

Y1 - 1999/12

N2 - Experimentally, decomposition of NO on the alkalized Pd/Al2O3 catalyst is remarkably enhanced at 825-1000 K. The enhancement in N2 yield may be due to the additional basic sites on the alkalized catalyst that can trap NO molecules. However, at T > 1000 K, due to the fact that the absorbed oxygen in subsurface or bulk of Pd was involved in the formation and desorption of oxygen molecules, yield of oxygen was enhanced.

AB - Experimentally, decomposition of NO on the alkalized Pd/Al2O3 catalyst is remarkably enhanced at 825-1000 K. The enhancement in N2 yield may be due to the additional basic sites on the alkalized catalyst that can trap NO molecules. However, at T > 1000 K, due to the fact that the absorbed oxygen in subsurface or bulk of Pd was involved in the formation and desorption of oxygen molecules, yield of oxygen was enhanced.

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JF - Chemosphere

SN - 0045-6535

IS - 13

ER -

Enhanced decomposition of NO on the alkalized PdO/Al₂O₃ catalyst

Abstract

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