Erecting buckybowls onto their edge: 2D self-assembly of terphenylcorannulene on the Cu(111) surface

Quirin S. Stöckl; Tsun Cheng Wu; Anaïs Mairena; Yao Ting Wu; Karl Heinz Ernst

doi:10.1039/c7fd00109f

Erecting buckybowls onto their edge: 2D self-assembly of terphenylcorannulene on the Cu(111) surface

Quirin S. Stöckl, Tsun Cheng Wu, Anaïs Mairena, Yao Ting Wu, Karl Heinz Ernst

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A 2D self-assembly of a C₃₂H₁₂ buckybowl on the Cu(111) surface has been studied by means of scanning tunnelling microscopy. Additional aromatic rings at the rim of the corannulene core cause the bowl-shaped molecule to stand on its edge. This adsorption mode allows distinct π-π and C-H⋯π interactions between the convex bowl surfaces as well as between the hydrogen-terminated rim and the convex bowl faces.

Original language	English
Pages (from-to)	429-437
Number of pages	9
Journal	Faraday Discussions
Volume	204
DOIs	https://doi.org/10.1039/c7fd00109f
Publication status	Published - 2017

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry

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10.1039/c7fd00109f

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title = "Erecting buckybowls onto their edge: 2D self-assembly of terphenylcorannulene on the Cu(111) surface",

abstract = "A 2D self-assembly of a C32H12 buckybowl on the Cu(111) surface has been studied by means of scanning tunnelling microscopy. Additional aromatic rings at the rim of the corannulene core cause the bowl-shaped molecule to stand on its edge. This adsorption mode allows distinct π-π and C-H⋯π interactions between the convex bowl surfaces as well as between the hydrogen-terminated rim and the convex bowl faces.",

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AU - Stöckl, Quirin S.

AU - Wu, Tsun Cheng

AU - Mairena, Anaïs

AU - Wu, Yao Ting

AU - Ernst, Karl Heinz

PY - 2017

Y1 - 2017

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AB - A 2D self-assembly of a C32H12 buckybowl on the Cu(111) surface has been studied by means of scanning tunnelling microscopy. Additional aromatic rings at the rim of the corannulene core cause the bowl-shaped molecule to stand on its edge. This adsorption mode allows distinct π-π and C-H⋯π interactions between the convex bowl surfaces as well as between the hydrogen-terminated rim and the convex bowl faces.

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Erecting buckybowls onto their edge: 2D self-assembly of terphenylcorannulene on the Cu(111) surface

Abstract

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