Fabrication of Bi2O3 thin film by thermal-enhanced electroplating

Chaur Chi Huang; Teng Yi Wen; Kuan-Zong Fung

Fabrication of Bi₂O₃ thin film by thermal-enhanced electroplating

Chaur Chi Huang, Teng Yi Wen, Kuan-Zong Fung

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

High-temperature fluorite structure Bi₂O₃ is a well-known solid electrolyte due to its high oxygen ion conductivity. The stabilization of cubic Bi₂O₃ may be enhanced by adding rare earth oxide. It was thought that phase transformation was caused by the presence of oxygen vacancies. In this study, Bi₂O₃ thin film was prepared by oxidation on the electroplated Bi. The effect of applied voltage on crystallization of metallic Bi thin film was investigated. The oxidation reaction of Bi with various crystalline orientations is discussed. Two preferred orientations, (102) and (202), appeared in XRD. After oxidation, β-Bi₂O₃ and α-Bi₂O₃ appeared due to the specific atomic configurations of (102) and (202). The microstructure observed by SEM showed microcracks due to lattice expansion from phase transformation. The volume changes from rhombohedral Bi to β-Bi ₂O₃ and α-Bi₂O₃ were estimated to be 16.73 and 19.14%.

Original language	English
Title of host publication	Solid Oxide Fuel Cells IX, SOFC IX
Subtitle of host publication	Materials - Proceedings of the International Symposium
Editors	S.C. Singhal, J. Mizusaki
Pages	1137-1141
Number of pages	5
Volume	PV 2005-07
Publication status	Published - 2005
Event	9th International Symposium on Solid Oxide Fuel Cells, SOFC IX - Quebec, Canada Duration: 2005 May 15 → 2005 May 20

Other

Other	9th International Symposium on Solid Oxide Fuel Cells, SOFC IX
Country	Canada
City	Quebec
Period	05-05-15 → 05-05-20

All Science Journal Classification (ASJC) codes

Engineering(all)

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@inproceedings{5e2db416675140ea8875447249bdf5ca,

title = "Fabrication of Bi2O3 thin film by thermal-enhanced electroplating",

abstract = "High-temperature fluorite structure Bi2O3 is a well-known solid electrolyte due to its high oxygen ion conductivity. The stabilization of cubic Bi2O3 may be enhanced by adding rare earth oxide. It was thought that phase transformation was caused by the presence of oxygen vacancies. In this study, Bi2O3 thin film was prepared by oxidation on the electroplated Bi. The effect of applied voltage on crystallization of metallic Bi thin film was investigated. The oxidation reaction of Bi with various crystalline orientations is discussed. Two preferred orientations, (102) and (202), appeared in XRD. After oxidation, β-Bi2O3 and α-Bi2O3 appeared due to the specific atomic configurations of (102) and (202). The microstructure observed by SEM showed microcracks due to lattice expansion from phase transformation. The volume changes from rhombohedral Bi to β-Bi 2O3 and α-Bi2O3 were estimated to be 16.73 and 19.14%.",

author = "Huang, {Chaur Chi} and Wen, {Teng Yi} and Kuan-Zong Fung",

year = "2005",

language = "English",

volume = "PV 2005-07",

pages = "1137--1141",

editor = "S.C. Singhal and J. Mizusaki",

booktitle = "Solid Oxide Fuel Cells IX, SOFC IX",

note = "9th International Symposium on Solid Oxide Fuel Cells, SOFC IX ; Conference date: 15-05-2005 Through 20-05-2005",

}

TY - GEN

T1 - Fabrication of Bi2O3 thin film by thermal-enhanced electroplating

AU - Huang, Chaur Chi

AU - Wen, Teng Yi

AU - Fung, Kuan-Zong

PY - 2005

Y1 - 2005

N2 - High-temperature fluorite structure Bi2O3 is a well-known solid electrolyte due to its high oxygen ion conductivity. The stabilization of cubic Bi2O3 may be enhanced by adding rare earth oxide. It was thought that phase transformation was caused by the presence of oxygen vacancies. In this study, Bi2O3 thin film was prepared by oxidation on the electroplated Bi. The effect of applied voltage on crystallization of metallic Bi thin film was investigated. The oxidation reaction of Bi with various crystalline orientations is discussed. Two preferred orientations, (102) and (202), appeared in XRD. After oxidation, β-Bi2O3 and α-Bi2O3 appeared due to the specific atomic configurations of (102) and (202). The microstructure observed by SEM showed microcracks due to lattice expansion from phase transformation. The volume changes from rhombohedral Bi to β-Bi 2O3 and α-Bi2O3 were estimated to be 16.73 and 19.14%.

AB - High-temperature fluorite structure Bi2O3 is a well-known solid electrolyte due to its high oxygen ion conductivity. The stabilization of cubic Bi2O3 may be enhanced by adding rare earth oxide. It was thought that phase transformation was caused by the presence of oxygen vacancies. In this study, Bi2O3 thin film was prepared by oxidation on the electroplated Bi. The effect of applied voltage on crystallization of metallic Bi thin film was investigated. The oxidation reaction of Bi with various crystalline orientations is discussed. Two preferred orientations, (102) and (202), appeared in XRD. After oxidation, β-Bi2O3 and α-Bi2O3 appeared due to the specific atomic configurations of (102) and (202). The microstructure observed by SEM showed microcracks due to lattice expansion from phase transformation. The volume changes from rhombohedral Bi to β-Bi 2O3 and α-Bi2O3 were estimated to be 16.73 and 19.14%.

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M3 - Conference contribution

AN - SCOPUS:31744432193

VL - PV 2005-07

SP - 1137

EP - 1141

BT - Solid Oxide Fuel Cells IX, SOFC IX

A2 - Singhal, S.C.

A2 - Mizusaki, J.

T2 - 9th International Symposium on Solid Oxide Fuel Cells, SOFC IX

Y2 - 15 May 2005 through 20 May 2005

ER -